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Mineralization Layers on Glasses of the Si-Ca-P-Mg System in a Physiologically Buffered Plasmatic Electrolyte

Journal Materials Science Forum (Volumes 587 - 588)
Volume Advanced Materials Forum IV
Edited by António Torres Marques, António Fernando Silva, António Paulo Monteiro Baptista, Carlos Sá, Fernando Jorge Lino Alves, Luís Filipe Malheiros and Manuel Vieira
Pages 12-16
DOI 10.4028/www.scientific.net/MSF.587-588.12
Online since June, 2008
Authors Sandra C.P. Cachinho, Rui N. Correia, Maria Helena F.V. Fernandes
Keywords In Vitro Tests, Apatite Layer, Bioglasses, Carbonate Buffer
Abstract Mineralization experiments on glasses of the Si-Ca-P-Mg system were carried out for 7 days in carbonated simulated inorganic plasma (CSIP) buffered with CO2/HCO3 -. This method enables physiological buffering of the solution within the 7.3–7.4 pH interval by maintaining a HCO3 - concentration between 24 and 27 mmol.L-1, which is the normal concentration range in blood plasma. XRD, SEM/EDS and FTIR were used to characterise the glass surfaces. All glasses exhibited an apatite-like deposit whose Ca/P ratio was dependent on glass composition.
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