Paper Title:
Immobilisation of Ferricinium Cation into ETS-10 by Ion Exchange under Microwave Irradiation
  Abstract

The microporous titanosilicate ETS-10 was subjected to three cycles of ferricinium ion ([(η5-C5H5)2Fe]+, Fc+) exchange by using aqueous solutions of ferricinium hexafluorophosphate and microwave-assisted heating. The resultant hybrid inorganic-organometallic (ETS-10/Fc+) materials were characterised by elemental analysis, ICP-AES, FTIR and Raman spectroscopy, powder X-ray diffraction (XRD), scanning electron microscopy (SEM), diffuse reflectance (DR) UV-Vis, 29Si and 23Na solid-state NMR. The results support the successful inclusion of Fc+ in the pores of the inorganic host by ion exchange of extra-framework sodium and potassium ions.

  Info
Periodical
Materials Science Forum (Volumes 587-588)
Edited by
António Torres Marques, António Fernando Silva, António Paulo Monteiro Baptista, Carlos Sá, Fernando Jorge Lino Alves, Luís Filipe Malheiros and Manuel Vieira
Pages
453-457
DOI
10.4028/www.scientific.net/MSF.587-588.453
Citation
A. C. Coelho, P. Brandão, A. M. dos Santos, J. Rocha, I. S. Gonçalves, "Immobilisation of Ferricinium Cation into ETS-10 by Ion Exchange under Microwave Irradiation", Materials Science Forum, Vols. 587-588, pp. 453-457, 2008
Online since
June 2008
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$32.00
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