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Ga-Modified Nanostructured ZnO: Characterization and Application in Dye-Sensitized Solar Cells

Journal Materials Science Forum (Volumes 591 - 593)
Volume Advanced Powder Technology VI
Edited by Lucio Salgado and Francisco Ambrozio Filho
Pages 13-17
DOI 10.4028/www.scientific.net/MSF.591-593.13
Citation Agnaldo S. Gonçalves et al., 2008, Materials Science Forum, 591-593, 13
Online since August, 2008
Authors Agnaldo S. Gonçalves, Ana Flavia Nogueira, Marian R. Davolos, Naruhiko Masaki, Shozo Yanagida, Selma G. Antônio, Carlos de Oliveira Paiva-Santos
Keywords Dye Sensitized Solar Cell, GZO, Nanostructured Films, ZnO:Ga
Abstract

ZnO has received great attention in many applications due to its electronic and optical properties. We report on the preparation of ZnO and gallium-containing ZnO (ZnO:Ga) nanoparticles by the precipitation method. The nanoparticles have the wurtzite structure and a high crystallinity. Gallium ions are present as Ga3+, as evidenced by the binding energies through XPS. Porosity and surface area of the powder increased under increasing gallium level, explained by the smaller particle size of ZnO:Ga samples compared with ZnO. The estimated optical band gap of ZnO was 3.2 eV, comparable to ZnO:Ga.

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