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Positronium Thermalization Process in Nanoporous Materials and its Influence on the Shape of PALS Spectrum

Journal Materials Science Forum (Volume 607)
Volume Positron and Positronium Chemistry
Edited by S. J. Wang, Z. Q. Chen, B. Wang and Y. C. Jean
Pages 39-41
DOI 10.4028/www.scientific.net/MSF.607.39
Online since November, 2008
Authors Jerzy Kansy, Radosław Zaleski
Keywords Nanoporous Materials, PALS Spectrum, Porosimetry, Positron Annihilation
Abstract A new method of analysis of PALS spectra of porous materials is proposed. The model considers both the thermalization process of positronium inside the pores and the pore size distribution. The new model is fitted to spectra of mesoporous silica MCM-41 and MSF. The resulting parameters are compared with parameters obtained from fitting the “conventional” models, i.e. a sum of exponential components with discrete or/and distributed lifetimes.
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