Modelling Flue Gas Desulfurization Using Pyrolusite Pulp in a Jet Bubbling Reactor

A mathematical model for flue gas desulfurization using pyrolusite pulp in jet bubbling reactor (JBR) was described. Firstly, based on the concept of two stages mass balance with chemical reaction, two models were set up, for jet bubbling zone and rising bubble zone, respectively, according to the construction of JBR. The models consist of two coupling differential equations and were solved simultaneously by integral and separation of the variables. Then the SO2 absorption efficiency expression was developed, considering the great discrepancy existing between the gas-side mass transfer coefficients of the jet bubbling zone and gas bubble rising zone. The final expression associates SO2 absorption efficiency with process conditions and JBR structure parameters, which can give some instruction and guidance for the study of reactor operation process. Predicted results from the theoretical model, including effect of pH value of the pulp, flue gas temperature and inlet SO2 concentration of flue gas on SO2 absorption efficiency, were found to be in good agreement with experimental data obtained in a jet bubbling reactor. The model provides a basis for the process scale up and operating guide.