Paper Title:
TEM Investigations of Graphene on 4H-SiC(0001)
  Abstract

Transmission Electron Microscopy (TEM) investigations of graphene layers on Si terminated 4H-SiC(0001) are presented. The graphene layers have been grown in a standard method using decomposition of silicon carbide. Two kind of graphene layers have been investigated: 1) grown on substrates with on-axis orientation, 2) grown on substrates with 4° and 8° off-axis orientation in respect of c-axis of SiC. In the case of 0° orientation the high resolution TEM micrographs revealed that a thin layer graphene is present: 1-3 monolayers were obtained. It was found that the first carbon layer was about 2Å from the SiC surface. This result indicates that a strong covalent bonds between carbon layer and silicon atoms on the SiC surface exist. The subsequent graphene layers have been found spaced by 3.4 Å - similar as in the graphite. That indicates a weak van der Waals bonding between subsequent carbon layers. In the case of 4° and 8° off-axis orientation a thicker layer of about 5-6 monolayers of graphene were obtained. Relative spacings of graphene layers were the same as in the case of on-axis orientation.

  Info
Periodical
Materials Science Forum (Volumes 615-617)
Edited by
Amador Pérez-Tomás, Philippe Godignon, Miquel Vellvehí and Pierre Brosselard
Pages
207-210
DOI
10.4028/www.scientific.net/MSF.615-617.207
Citation
J. Borysiuk, W. Strupiński, R. Bożek, A. Wysmolek, J. M. Baranowski, "TEM Investigations of Graphene on 4H-SiC(0001)", Materials Science Forum, Vols. 615-617, pp. 207-210, 2009
Online since
March 2009
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$32.00
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