Paper Title:
Growth Stresses and Phase Development in Nanostructured Oxide Scales Formed on Iron Aluminides
  Abstract

The evolution of phase composition and growth stresses in oxide scales growing on the polycrystalline Fe-15at.%Al alloy at 700°C in air was studied by in-situ synchrotron X-ray diffraction and X-ray photoelectron spectroscopy. The oxidation kinetics was determined by thermogravimetry. The results showed that, under these conditions, metastable -Al2O3 appears only during the first minutes of oxidation and the main oxides formed since the early oxidation are -Al2O3 and -Fe2O3. High volume fractions of -Fe2O3 caused accelerated oxidation rates in the first hours. -Al2O3 and -Fe2O3 grow epitaxially, evolving compressive and tensile growth stresses, respectively.

  Info
Periodical
Materials Science Forum (Volumes 638-642)
Main Theme
Edited by
T. Chandra, N. Wanderka, W. Reimers , M. Ionescu
Pages
2903-2908
DOI
10.4028/www.scientific.net/MSF.638-642.2903
Citation
P. Brito, H. Pinto, A. Rothkirch, A. Pyzalla, "Growth Stresses and Phase Development in Nanostructured Oxide Scales Formed on Iron Aluminides", Materials Science Forum, Vols. 638-642, pp. 2903-2908, 2010
Online since
January 2010
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