Paper Title:

Deep UV Raman Spectroscopy of Epitaxial Graphenes on Vicinal 6H-SiC Substrates

Periodical Materials Science Forum (Volumes 645 - 648)
Main Theme Silicon Carbide and Related Materials 2009
Edited by Anton J. Bauer, Peter Friedrichs, Michael Krieger, Gerhard Pensl, Roland Rupp and Thomas Seyller
Pages 611-614
DOI 10.4028/www.scientific.net/MSF.645-648.611
Citation Susumu Kamoi et al., 2010, Materials Science Forum, 645-648, 611
Online since April, 2010
Authors Susumu Kamoi, Noriyuki Hasuike, Kenji Kisoda, Hiroshi Harima, Kouhei Morita, Satoru Tanaka, Akihiro Hashimoto
Keywords Graphen, Raman Spectroscopy
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Abstract

We report microscopic Raman scattering studies of epitaxial graphene grown on SiC substrates using a deep-ultraviolet (UV) laser excitation at 266 nm to elucidate the interaction between the graphene layer and the substrate. The samples were grown on the Si-face of vicinal 6H-SiC (0001) substrates by sublimation of Si from SiC. The G band of the epitaxial graphene layer was clearly observed without any data manipulation. Increasing the number of graphene layers, the peak frequency of the G-band decreases linearly, while the peak width and the intensity increase. The G-band frequency of the graphene layers on SiC is higher than those of exfoliated graphene, which has been ascribed to compression from the substrate.