Materials Science Forum Vol. 658

Abstract: Changes in morphology during the oxidation of iron nanoparticles and nanowires at 473~ 873 K have been studied by transmission electron microscopy. Iron nanoparticles and wires become hollow nanoparticles and nanotubes of Fe3O4 at temperatures below 673 K as a result of vacancy aggregation in the oxidation process. On the other hand, the hollow magnetite transforms into duplex porous structures with an interior nanopore and additional nanovoids at higher temperatures above 673 K, where the shrinkage of hollow nanoparticles and nanotubes starts and the phase transformation from Fe3O4 to -Fe2O3 occurs. Transition in porous structure seems to be related to the outward diffusion of vacancies from interior pore and the phase transformation in the shrinkage process.

Abstract: Lotus-type porous magnesium ingots were fabricated in pressurized hydrogen atmosphere through a mold casting technique. The mold consists of two cooling blocks placed at the bottom and one lateral side. It was found that the pores started to grow upwards and horizontally and the both directional pores collapsed and then shifted to the direction. Such anisotropic growth of pores is in good agreement with the map of temperature gradient predicted by two-dimensional finite differential analysis.

Abstract: Porous Al-5mass%Ti alloys were fabricated using a continuous casting technique in a hydrogen atmosphere, and the effects of transfer velocity (V) and the peritectic solidification process on the pore morphology and matrix microstructure were examined. In the case of V = 0.5 mm/min, columnar microstructure and directional pores grow along the transfer direction. The Al3Ti phases are formed in localized regions of matrix part, and however, they do not suppress the growth of directional pores in the other regions. In the case of 5.0 mm/min, because needle-like Al3Ti phases grow along the transfer direction, directional pores can grow between them. On the other hand, in the case of 10.0 mm/min, spherical pores surrounded by equiaxed peritectic microstructure and homogeneously distributed Al3Ti phases are formed, because the primary α -Al and Al3Ti phases probably prevent the growth of directional pores.

Abstract: Lotus-type porous aluminum was fabricated by continuous casting technique in mixture gas of hydrogen and argon at various transfer velocities in order to understand formation process of pores. The porosity and pore diameter decrease with increasing transfer velocity. The transfer velocity dependence of the porosity in lotus aluminum is different from that in other lotus metals such as stainless steel and copper. It is considered that the difference is attributed to lower solubility in aluminum than that in other metals.

Abstract: Lotus-type porous carbon steel (lotus carbon steel) plates were fabricated by continuous casting technique in a pressurized nitrogen atmosphere. The experiments were done both with adding 0.3wt% of NiO powder in molten carbon steel in a ceramic crucible and without NiO powder. The lotus carbon steel fabricated without NiO powder under nitrogen pressures of 0.1 and 0.5 MPa had single pores which grew independently. On the other hand, the lotus carbon steel fabricated with adding NiO powder had pores which coalesced each other and became in irregular shapes. Under nitrogen pressure of 2.5 MPa, the pores formed with adding NiO powder were smaller than that formed without NiO powder. The porosity increased by adding NiO powder in every pressurized nitrogen atmosphere. From these results, NiO powder in molten carbon steel is considered to act as nucleation sites for pores at the solid-liquid interface and to increase of the pore number.

Abstract: Lotus-type porous metal with many straight pores is attractive as a heat sink because larger heat transfer capacity is obtained due to the small diameter of the pores. The heat transfer capacity of the lotus-type porous copper heat sink was calculated using the model with the pores of uniform diameters. However, actual lotus-type porous metals have a distribution of pore diameter. In the present work, we investigated the lotus-type porous copper fin model by considering size distribution of the lotus-type porous copper fin. Prediction of the heat transfer characteristics for the lotus-type porous copper heat sink shows a good agreement with the experimental data.

Abstract: Currently, there are cast iron pipe, protective coating steel pipe, PE pipe, GRP (Glass-Fiber Reinforced Pipe), PVC pipe etc in use in Korea. Since there is rather very low recognition of synthetic resins pipe among those in case of Korea, the kind of pipes for use is very few compared with the actual performance. Once analyzing foreign data, synthetic resin pipes are widely used in even drainpipe and items for piping such as connecting parts are diverse and accessories of piping for general use are being laid underground. It is necessary to mine pipes with selection of various kinds of pipes considering surrounding environment and local circumstances in Korea. This study evaluated the features of soil pressure using load-strain feature and simulated scale down box test through 3-point deflection test for the evaluation of basic features by vertical load such as breakage of PVC pipe and leakage in mining environment in which live loads and cavity exist.

Abstract: The metal/ceramic composite coatings that consisted of (Ni-22Cr-10Al-1Y) and (ZrO2-25CeO2-2.5Y2O3) were prepared by the air plasma spray (APS) method. The as-sprayed coatings consisted of metal-rich and ceramic-rich regions, between which the -Al2O3 oxide stringers existed owing to the oxidation of Al in (Ni-22Cr-10Al-1Y) during APS. The composite coatings were hot corroded at 800 and 900 oC for up to 50 h in 75%NaCl-25%Na2SO4 molten salt. The corrosion products that formed on the coating surface during hot corrosion were mostly dissolved off into the molten salt. The scales that remained on the coating surface consisted primarily of Cr2O3, and a lesser amount of NiO and Al2O3. The corrosion resistance decreased, as not only the test temperature and time but also the amount of metal in the coating increased.

Abstract: The formation process of oxide nanotube via metal oxidation reaction was studied by transmission electron microscopy for Cu, Fe, and Ni nanowires. Cu2O and Fe3O4 nanotubes were formed after the oxidation of Cu and Fe nanowires with a diameter of 55 nm in air at 423 and 573 K for 3.6 ks, respectively. Both Cu2O and Fe3O4 nanotubes had a cylindrical interior pore with uniform diameter. On the other hand, Ni nanowires became bamboo-like structures of NiO with separate interior pores after oxidation at 673 K for 7.2 ks. The formation of the interior pores in Cu2O and Fe3O4 nanotubes and NiO bamboo-like structures can be explained by the rapid outward diffusion of metal ions through the oxide layers and the clustering of excess vacancies.

Abstract: This paper reports on the effect of air plasma on the FRP surface wettability via change of the water contact angle. The aim is to alter the surface in a manner and scale resulting in stronger bonding strength between FRP and wood. The specimens are exposed to the direct current discharge. The irradiation time and power are variables. Goniometry is employed to determine the contact angle of FRP surface. The plasma treatment leads to radical generation and activation of such agents as oxygen, thus the surface contact angle decreases significantly. The shear strength of samples of wood reinforced by treated FRP is also given to show the bond quality at the FRP-wood interface.