Paper Title:

Anisotropic Hydrogel Formation: Effect of Boundary Condition

Periodical Materials Science Forum (Volume 687)
Main Theme Functional and Electronic Materials
Edited by Chengming Li, Chengbao Jiang, Zhiyong Zhong and Yichun Zhou
Pages 567-570
DOI 10.4028/www.scientific.net/MSF.687.567
Citation Naoko Tomita et al., 2011, Materials Science Forum, 687, 567
Online since June, 2011
Authors Naoko Tomita, Isamu Rokugawa, Hiromi Toyama, Takao Yamamoto, Toshiaki Dobashi
Keywords Anisotropic Hydrogel, Boundary Condition, Chitosan (CS), Dialysis
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Abstract

Anisotropic gelation has been studied by immersing chitosan in aqueous acetic acid sandwiched by a pair of square cover glasses into aqueous sodium hydroxide. The shape of the gel front line initially remained a square, whereas it approached a circle with immersion time. The time course of the distance between the side of the cover glasses and the gel front line xs was expressed initially as scaled proportional relationship (xs/L)2 =2K(t/L2), where t is the immersion time, L; the length of the side of the cover glasses and K; a constant. The characteristic behavior was independent of chitosan concentration.