Paper Title:
Synthesis and Electrochemical Performances of Electroactive Nano Layered Organic-Inorganic Perovskite Containing Trivalent Iron Ion
  Abstract

A steady layered organic-inorganic perovskite hybrid containing Fe3+ was prepared in the air with phenosafranine as organic sheets, the Fe(CN)63- as inorganic sheets. We utilized the Fe(CN)63- as inorganic sheets of perovskite hybrids, which may help to stabilize the unusual metal-deficient layered structures. The results of X-ray diffractometry (XRD) and scanning electron microscopy (SEM) show that the hybrid is typical layered perovskite structure. The hybrid was mixed with paraffin to form a hybrid paste for the hybrid paste electrode. Electrochemical characteristics of carbon paste electrode (CPE) modified by hybrid were investigated with cyclic voltammetry. The modified electrode can accelerate the electron-transfer to improve the electrochemical reaction reversibility and be use for the determination of chemicals. The interactions between sodium nitrite (NaNO2), sodium bromide (NaBr), hydroxylammonium chloride (NH2OH·HCl), hydroquinone (C6H6O2) with hybrid were studied. The modified electrode exhibits good electrochemical activity. The hybrid can be used as electrochemical materials.

  Info
Periodical
Edited by
Rongming Wang, Ying Wu and Xiaofeng Wu
Pages
307-313
DOI
10.4028/www.scientific.net/MSF.688.307
Citation
J. Wu, X. Zhou, H. X. Liu, Z. D. Lin, G. F. Chen, "Synthesis and Electrochemical Performances of Electroactive Nano Layered Organic-Inorganic Perovskite Containing Trivalent Iron Ion", Materials Science Forum, Vol. 688, pp. 307-313, 2011
Online since
June 2011
Export
Price
$32.00
Share

In order to see related information, you need to Login.

In order to see related information, you need to Login.

Authors: Peng Chao Kang, Guo Qin Chen, Gao Hui Wu
Abstract:Nano-SiCp/MoSi2 composites with different SiC volume fraction have been synthesized by in situ reactive hot press sintering with the milled...
150
Authors: Yu Cui Hao, Li Shen, Zhi Ai
Chapter 9: Energy Chemical Engineering
Abstract:Platinum particles modified glassy carbon electrode(Pt/GCE)was prepared by electrochemically deposite. The electrochemica1 behaviors of...
2291
Authors: Jian Ya Wang, Shui Xin Peng, Bin Xue, Jing Han Zhai
Chapter 2: Analytical and Environmental Chemistry, Waste Disposal and Utilization Technology
Abstract:The electrochemical oxidation of 4-chlorophenoxyacetic acid on Ti/SnO2-Sb2O5/PbO2 electrode was studied by cyclic voltammetry in this paper....
225
Authors: Peng Song, Jian Sheng Lu
Chapter 2: Material Science, Materials Processing and Manufacturing Processes Technology
Abstract:Pt-modified nickel aluminide coatings have been more widely used for protection of jet-engine components against high-temperature oxidation....
383
Authors: Mohd Sazwan Affendi Rasiman, Fadhlul Wafi Badrudin, Muhamad Kamil Yaakob, M.F.M. Taib, Ab Malik Marwan Ali, Muhd Zu Azhan Yahya, Oskar Hasdinor Hassan
Chapter 9: Materials and Technologies in Electronics and Optoelectronics
Abstract:First-principles calculations based on the DFT approximated by GGA-PBEsol scheme has been utilized to predict the structural and electronic...
485