Paper Title:
Improved Corrosion Resistance of Superheater Materials in H2O Containing Environments Using Mn-Diffusion Coatings
  Abstract

The oxidation resistance of ferritic-martensitic 9% chromium steels in water vapour containing atmospheres is not yet satisfactory. The chromia layer provides little protection because water vapour in the atmosphere is known to promote the formation of the volatile chromium species CrO2(OH)2. If a chromium manganese spinel is formed instead, the vapour pressure of the oxy-hydroxide is greatly reduced and evaporation can largely be avoided. Enrichment of the substrate with manganese was achieved using three different processes: using (i) a sputtering technique, (ii) electrochemical deposition both followed by a diffusion heat treatment, (iii) the pack cementation method. Uniform diffusion of manganese was obtained with all of the investigated processes. The improved oxidation behaviour of the coated samples in synthetic air with 10% water vapour at 650°C was demonstrated.

  Info
Periodical
Edited by
Toshio Maruyama, Masayuki Yoshiba, Kazuya Kurokawa, Yuuzou Kawahara and Nobuo Otsuka
Pages
330-335
DOI
10.4028/www.scientific.net/MSF.696.330
Citation
D. Schmidt, M. Schütze, "Improved Corrosion Resistance of Superheater Materials in H2O Containing Environments Using Mn-Diffusion Coatings", Materials Science Forum, Vol. 696, pp. 330-335, 2011
Online since
September 2011
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$32.00
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