Paper Title:

Electronic Chemical Properties of Vanadium Doped TiO2 for Photocatalytic Degradation of BTEX

Periodical Materials Science Forum (Volume 700)
Main Theme Advanced Materials and Nanotechnology
Edited by B. J. Ruck and T. Kemmitt
Pages 223-226
DOI 10.4028/www.scientific.net/MSF.700.223
Citation Laksana Laokiat et al., 2011, Materials Science Forum, 700, 223
Online since September, 2011
Authors Laksana Laokiat, Pongtanawat Khemthong, Nurak Grisdanurak
Keywords PECVD, Photocatalytic Degradation, Vanadium Doping
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Abstract

V-doped TiO2 (V-TiO2) was synthesised using solvothermal technique and immobilised onto fibreglass cloth (FGC). The XRD pattern of doped sample showed slight positive shift to higher angle indicating that the V ions were well substituted into the Ti lattices. The band-gap energy of V-TiO2 was lower than that of P25, pure TiO2, (3.28 eV for P25 and 2.90 eV for V-TiO2) demonstrating it could be excited by visible light. The XANES spectra of the Ti K-edge transition indicated most Ti ions were in the tetravalent state with octahedral coordination. The A2 species on the surfaces of V-TiO2 were found to be the main active sites during photocatalytic degradation of BTEX under visible light irradiation.