Electronic Chemical Properties of Vanadium Doped TiO2 for Photocatalytic Degradation of BTEX
| Periodical | Materials Science Forum (Volume 700) |
|---|---|
| Main Theme | Advanced Materials and Nanotechnology |
| Edited by | B. J. Ruck and T. Kemmitt |
| Pages | 223-226 |
| DOI | 10.4028/www.scientific.net/MSF.700.223 |
| Citation | Laksana Laokiat et al., 2011, Materials Science Forum, 700, 223 |
| Online since | September, 2011 |
| Authors | Laksana Laokiat, Pongtanawat Khemthong, Nurak Grisdanurak |
| Keywords | PECVD, Photocatalytic Degradation, Vanadium Doping |
| Price | US$ 28,- |
V-doped TiO2 (V-TiO2) was synthesised using solvothermal technique and immobilised onto fibreglass cloth (FGC). The XRD pattern of doped sample showed slight positive shift to higher angle indicating that the V ions were well substituted into the Ti lattices. The band-gap energy of V-TiO2 was lower than that of P25, pure TiO2, (3.28 eV for P25 and 2.90 eV for V-TiO2) demonstrating it could be excited by visible light. The XANES spectra of the Ti K-edge transition indicated most Ti ions were in the tetravalent state with octahedral coordination. The A2 species on the surfaces of V-TiO2 were found to be the main active sites during photocatalytic degradation of BTEX under visible light irradiation.