Paper Title:

Photocatalytic Cement by TiO2 Addition

Periodical Materials Science Forum (Volume 712)
Main Theme Photocatalytic Materials & Surfaces for Environmental Cleanup
Edited by Rajesh J. Tayade
Pages 65-72
DOI 10.4028/www.scientific.net/MSF.712.65
Citation Pradeepan Periyat et al., 2012, Materials Science Forum, 712, 65
Online since February, 2012
Authors Pradeepan Periyat, A.S. Divya, K.G.K. Warrier
Keywords Anatase, Cement, Photocatalyst, Sol-Gel (SG), TiO2
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Abstract

Photocatalytically active TiO2 and silica doped TiO2 (Si-TiO2) synthesised using an aqueous sol-gel method and is characterised by particle size analysis, XRD, diffuse reflectance spectra and BET measurements. The photocatalytic analysis using methylene blue proved that the Si-TiO2 possesses higher activity than pure TiO2. This Si-TiO2 having higher photo-catalytic activity was incorporated into white portland cement and this modified cement exhibited photo-catalytic activity as evaluated by using methylene blue degradation experiments. This novel work is considered to be useful for further development of self-cleaning cements. Moreover silica doped to TiO2 improved surface area and thermal stability of anatase TiO2 significantly. At 800 ะพC, 100 percentage anatase phase was obtained for Si-TiO2 whereas pure TiO2 showed 100 percentage rutile phase at the same temperature and surface aera of the Si-TiO2 was 93 m2/g while pure TiO2 showed only 2 m2/g.