Electrical Nanocharacterization of Epitaxial Graphene/Silicon Carbide Schottky Contacts

Article Preview

Abstract:

Epitaxial graphene fabricated by thermal decomposition of the Si-face of silicon carbide (SiC) forms a defined interface to the SiC substrate. As-grown monolayer graphene with buffer layer establishes an ohmic interface even to low-doped (e. g. [N] ≈ 1015 cm-3) SiC, and a specific contact resistance as low as ρC = 5.9×10-6 Ωcm2 can be achieved on highly n-doped SiC layers. After hydrogen intercalation of monolayer graphene, the so-called quasi-freestanding graphene forms a Schottky contact to n-type SiC with a Schottky barrier height of 1.5 eV as determined from C-V analysis and core level photoelectron spectroscopy (XPS). This value, however, strongly deviates from the respective value of less than 1 eV determined from I-V measurements. It was found from conductive atomic force microscopy (C-AFM) that the Schottky barrier is locally lowered on other crystal facets located at substrate step edges. For very small Schottky contacts, the barrier height extracted from I-V curves approaches the value of 1.5 eV from C-V and XPS.

You might also be interested in these eBooks

Info:

Periodical:

Materials Science Forum (Volumes 778-780)

Pages:

1142-1145

Citation:

Online since:

February 2014

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2014 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

* - Corresponding Author

[1] K. V. Emtsev et al., Nat. Mater. 8, 203 (2009).

Google Scholar

[2] S. Hertel et al., Nat. Commun. 3, 957 (2012).

Google Scholar

[3] C. Riedl et al., Phys. Rev. Lett. 103, 246804 (2009).

Google Scholar

[4] S. Sonde et al., Phys. Rev. B 80, 241406(R) (2009).

Google Scholar

[5] F. Giannazzo et al., EuroPhys. Lett. 74, 686-692 (2006).

Google Scholar

[6] D. Waldmann, Manipulation and Characterization of Graphene on Silicon Carbide(0001), Shaker Verlag, Aachen, 2013, p.69.

Google Scholar

[7] J. H. Klootwijk & C. E. Timmering, ICMTS '04, 247–252 (2004).

Google Scholar