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Application of HPLC for the Analysis of Organic Additives in Cleaning Chemicals and Cleaning Mixtures

Journal Solid State Phenomena (Volumes 103 - 104)
Volume Ultra Clean Processing of Silicon Surfaces VII
Edited by Paul Mertens, Marc Meuris and Marc Heyns
Pages 221-226
DOI 10.4028/www.scientific.net/SSP.103-104.221
Citation S. Metzger et al., 2005, Solid State Phenomena, 103-104, 221
Online since April, 2005
Authors S. Metzger, Bernd O. Kolbesen
Keywords Complexing Agent Decomposition, HPLC-MS, MS/MS, Single Chemistry Cleaning
Abstract

The suitability of high performance liquid chromatography (HPLC) for the direct determination of the concentration of complexing agents for single chemistry cleaning is demonstrated. HPLC, coupled to a mass spectrometric detector (HPLC-MS) and two-dimensional mass spectrometry (MS/MS) have been applied for the investigation of the reactions involved in the decomposition of the complexing agents. The techniques described are useful for determining the stability of organic additives in wet chemical cleaning baths.

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