Paper Title:
Microwave Synthesis and Catalytic Applications of Novel Cobalt Incorporated Nickel Phosphate
  Abstract

The novel cobalt incorporated nickel phosphate, (CoNiPO4), has been synthesized from aqueous system with triethyl amine (TEA) as an organic template using the microwave assisted reaction system under weak basic conditions. Among various factors used for synthesis, the pH of the reactant mixture and homogeneous heating under microwave could be the decisive factor to form the cobalt incorporated microporous VSB-n type nickel phosphate with novel structural parameters and unique stacked sheet like morphology. Its ability to perform as heterogeneous catalyst was discovered in the aerial oxidation of ethylbenzene and liquid phase oxidation of styrene using aq. hydrogen peroxide as an oxidizing agent.

  Info
Periodical
Solid State Phenomena (Volume 119)
Edited by
Chang Kyu Rhee
Pages
279-282
DOI
10.4028/www.scientific.net/SSP.119.279
Citation
I. R. Shaikh, S. E. Park, "Microwave Synthesis and Catalytic Applications of Novel Cobalt Incorporated Nickel Phosphate", Solid State Phenomena, Vol. 119, pp. 279-282, 2007
Online since
January 2007
Export
Price
$32.00
Share

In order to see related information, you need to Login.

In order to see related information, you need to Login.

Authors: Peng Sun, Yan Kong, Jun Du, Xin Jie Xu, Jun Wang, Zhi Yun
Abstract:A serious of spherical Co-MCM-41s with different cobalt content was synthesized and characterized by XRD, SEM, N2 isotherms and ICP...
131
Authors: Xian Da He, Hong Qi Ye, Qin Kuai, Kai Hua Xu, Hong Tao Han
Abstract:A novel solid-liquid reaction route has been developed to synthesize rodlike submicron cobalt oxalate via dissolution of cobalt powders by...
260
Authors: Feng Hua Bai, Yin Xia Zhang, Hai Quan Su, Xue Fen Li, Hui Pan, Xu Zhuang Yang
Abstract:The effect of precursors of Co/γ-Al2O3 catalysts prepared from Co(NO3)2 and...
684
Authors: Aditya Sharma, D.K. Sharma, Kapil Sharma, Vipin Kumar
Chapter 3: Nanomaterials
Abstract:In this work, an effective and economic way of transition metal doping in tin oxide nanoparticles is presented. The x-ray diffraction (XRD)...
179
Authors: Siwaruk Chotiwan, Waritsara Bungmek, Sanya Prangsri-Aroon, Pinsuda Viravathana
Chapter 11: Energy Chemical Engineering and Processes
Abstract:The precalcined and calcined silica supported cobalt catalysts at 15, 20, and 25%Co were investigated by X-ray Absorption Spectroscopy (XAS)...
1413