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Ion Conducting Behaviors of Polymeric Composite Electrolytes Containing Mesoporous Silicates

Journal Solid State Phenomena (Volume 119)
Volume Nanocomposites and Nanoporous Materials VII
Edited by Chang Kyu Rhee
Pages 51-54
DOI 10.4028/www.scientific.net/SSP.119.51
Citation Seok Kim et al., 2007, Solid State Phenomena, 119, 51
Online since January, 2007
Authors Seok Kim, Sung Goo Lee, Soo Jin Park
Keywords Crystallinity, Ionic Conductivity, Poly(Ethylene Oxide) (PEO), Polymeric Electrolyte Composites, Silicates
Abstract

Polymeric composite electrolytes (PCE) based on poly(ethylene oxide) (PEO) and mesoporous silicates as a filler material were fabricated, and investigated for understanding the effects of filler addition into the polymer matrix on the ionic conductivity. For a lithium battery application, it is necessary to increase ion conductivity of PCE by modification of microstructure. The ionic conductivity was enhanced with increasing MCM-41 contents due to the decreased crystallinity of PEO. Furthermore, the regular mesoporous structure could be functioned as an ion transfer channel for high ion mobility.

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