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Luminescence of MWO4 (M =Ca, Sr, Ba and Pb) Prepared by Solvothermal Reaction

Journal Solid State Phenomena (Volumes 124 - 126)
Volume Advances in Nanomaterials and Processing
Edited by Byung Tae Ahn, Hyeongtag Jeon, Bo Young Hur, Kibae Kim and Jong Wan Park
Pages 315-318
DOI 10.4028/www.scientific.net/SSP.124-126.315
Citation Titipun Thongtem et al., 2007, Solid State Phenomena, 124-126, 315
Online since June, 2007
Authors Titipun Thongtem, Sulawan Kaowphong, Somchai Thongtem
Keywords Luminescence Spectra, MWO4, Solvothermal Reaction
Abstract

MWO4 (M = Ca, Sr, Ba and Pb) was solvothermally prepared using metallic nitrates and sodium tungstate in 25/5 volume ratios of glycerol/water (SGL) and propylene glycol/water (SPG) at 160 oC for 6 h. XRD revealed the presence of MWO4 single phase with tetragonal scheelite structure. The strong W-O stretching band of WO4 tetrahedrons was detected at 705-875 cm-1. The product images show nano-sized particles in basic SGL and SPG solvents and flower-like particles in SPG solvent with pH of 6.7. Central peaks of the luminescent spectra are 445, 446, 443 and 440 nm, respectively.

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