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Advances in Structural Characterization of Thin Film Nanocrystalline Silicon for Photovoltaic Applications

Journal Solid State Phenomena (Volumes 131 - 133)
Volume Gettering and Defect Engineering in Semiconductor Technology XII
Pages 33-38
DOI 10.4028/www.scientific.net/SSP.131-133.33
Online since October, 2007
Authors Alessia Le Donne, Simona Binetti, Giovanni Isella, Bernard Pichaud, Michael Texier, Maurizio Acciarri, Sergio Pizzini
Keywords Glassy and Crystalline Substrates, High Resolution Transmission Electron Microscopy (HRTEM), Nanocrystalline Silicon, Raman, Structural Properties, X-Ray Diffraction (XRD)
Abstract The knowledge and control of the structural and morphological properties of nanocrystalline silicon is a fundamental requisite for its proper application in photovoltaics. To this purpose, nanocrystalline silicon films grown by Low Energy Plasma Enhanced Chemical Vapour Deposition (LEPECVD) technique on different kinds of substrates were submitted to a systematic characterization using Raman spectroscopy, X-ray diffraction (XRD) and high-resolution transmission electron microscopy (HRTEM). The results showed that the nature of the film substrate induces deep changes in the structural properties of the deposited films. The importance of a Raman in–depth analysis for an accurate determination of the sample structure has been also demonstrated.
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