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The Effect of Si/Al Ratio on Selective Catalytic Reduction of NOx with NH3 over Pt/Al-SBA-15

Journal Solid State Phenomena (Volume 135)
Volume Nanocomposites and Nanoporous Materials VIII
Edited by Chang Kyu Rhee
Pages 61-64
DOI 10.4028/www.scientific.net/SSP.135.61
Citation Min Kang et al., 2008, Solid State Phenomena, 135, 61
Online since February, 2008
Authors Min Kang, Jae Hyun Park, Eun Duck Park, Ji Man Kim, Dae Jung Kim, Jae Eui Yie
Keywords AI-SBA-15, Aluminum Content, Low Temperature, NH3-SCR, Pt
Abstract

The selective catalytic reduction of NOx with NH3 (NH3-SCR) was investigated over Pt catalysts supported on various supports such as alumina, ZSM-5, SBA-15, and Al-SBA-15 with different amounts of alumina. Among them, Pt catalysts supported on Al-SBA-15 showed the higher NOx conversion at low temperatures than those of others. These also showed high NOx conversions over a wide reaction temperature. As the Si/Al ratio in Al-SBA-15 decreased, the NH3-SCR activity increased. This was closely related to the amount of strongly-adsorbed NH3.

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