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Order-Disorder Transitions and Thermodynamic Properties of M-Type Hexaferrites

Journal Solid State Phenomena (Volume 150)
Volume Solid Phase Transformations II
Edited by J. Čermák and I. Stloukal
Pages 101-121
DOI 10.4028/www.scientific.net/SSP.150.101
Online since January, 2009
Authors S.C. Parida
Keywords Curie Temperature, Differential Scanning Calorimetry, Isobaric Molar Heat Capacity, Lattice Heat Capacity, Magnetic Heat Capacity, Magnetic Ordering, Magnetoplumbite Structure, M-Type Hexaferrite, Order-Disorder Transformation, Phase Transition, Thermodynamic Properties
Abstract Owing to the technological importance of M-type hexaferrites of general formula MFe12O19 (M = Ba, Sr and Pb) and their substituted analogues, a staggering number of research activities on their synthesis, magnetic properties and thermal properties are being pursued in recent years. However, many critical issues on the effect of aliovalent ion substitution either on the M-site or Fe-sites are still unexplored. This paper deals with a survey of crystallochemical and thermodynamic properties of this important class of ferrimagnetic oxides.
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