Paper Title:
Structure-Reactivity Relationships of Anatase and Rutile TiO2 Nanocrystals Measured by In Situ Vibrational Spectroscopy
  Abstract

A comprehensive analysis of structural-reactivity relations on TiO2 nanocrystals is presented. Using an interplay between TEM, X-ray diffraction and vibrational spectroscopy of well-defined anatase and rutile TiO2 nanocrystals correlations between the adsorbate structure of formic acid and the corresponding photo-induced decomposition rate are described. It is demonstrated that the detailed bonding configuration determines the decomposition rate. Generalizations and implications of the findings are discussed.

  Info
Periodical
Solid State Phenomena (Volume 162)
Edited by
Maria K. Nowotny and Janusz Nowotny
Pages
203-219
DOI
10.4028/www.scientific.net/SSP.162.203
Citation
L. Österlund, "Structure-Reactivity Relationships of Anatase and Rutile TiO2 Nanocrystals Measured by In Situ Vibrational Spectroscopy", Solid State Phenomena, Vol. 162, pp. 203-219, 2010
Online since
June 2010
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