Paper Title:

Microstructures and Thermoelectric Properties of (Bi2Te3)1-X/(CdTe)x Composites

Periodical Solid State Phenomena (Volume 170)
Main Theme Solid Compounds of Transition Elements
Edited by J.-L. Bobet, B. Chevalier and D. Fruchart
Pages 41-46
DOI 10.4028/www.scientific.net/SSP.170.41
Citation Horng Jyh Gao et al., 2011, Solid State Phenomena, 170, 41
Online since April, 2011
Authors Horng Jyh Gao, Wu Ruei Huang, Ching Cherng Wu, Yung Kang Kuo, Ching Hwa Ho
Keywords (Bi2Te3)1-x/(CdTe)x, Thermoelectric Material, Two-Component Composites
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Abstract

In this study, Bi2Te3 was selected as a matrix material and an immiscible semiconductor material CdTe with a wider energy band gap was precipitated to form microstructures in it. For this purpose, a series of two-component composites (Bi2Te3)1-x/(CdTe)x, with x = 0.01, 0.05, 0.1, 0.15, 0.2 were prepared by melting, high speed rocking and quenching technique. The composition and microstructure of these two-component composites were examined by X-ray and SEM. Thermoelectric properties including Seebeck coefficient, electric resistivity, and thermal conductivity were measured from 30 K to 400 K. The compositional and temperature dependence of the microstructure and thermoelectric properties of (Bi2Te3)1-x/(CdTe)x composites were discussed. It is found that (Bi2Te3)0.99/(CdTe)0.01 exhibits a better thermoelectric performance than that of Bi2Te3 at elevated temperatures. The figure of merit (ZT) of (Bi2Te3)0.99/(CdTe)0.01 is about 0.64 at 400 K.