Papers by Author: Bernd Baufeld

Abstract: Electrophoretic deposition (EPD) allows the fabrication of ceramic coatings at lower cost and higher speed than most other deposition techniques. The processing consists of powder deposition from a suspension under the influence of an electric field and subsequent consolidation of the coating by sintering. Adherent zirconia coatings with coating thicknesses up to 0.1 mm were obtained from different suspensions, one methyl-ethyl-ketone and the other ethanol based. The standard sintering temperature is 1200°C, which easily may damage or change the substrate and also means high production costs. In order to reduce the sintering temperature, suspensions with the addition of ZrN were investigated. Due to reaction bonding, sintering in air at a remarkable low temperature of 1000°C was successful. The elastic modulus of the EPD coatings has been derived from impulse excitation experiments and the thermal conductivity from laser flash analysis. The elastic modulus was about 22 GPa and the thermal conductivity between 0.4 and 0.6 W/(m•K) at room temperature, both decreasing slightly with temperature. Especially the exceptionally low thermal conductivity makes EPD coatings a promising candidate for thermal barrier coatings.

Abstract: In order to obtain a protection against temperature and stress induced detrimental rumpling of the metal surface of turbine blades, thin ceramic coatings are suggested. As a cheap and fast method for the fabrication of a ceramic zirconia coating, electrophoretic deposition on a Ni based superalloy is described. Crack free, 0.15 mm thick coatings with homogenous morphology were obtained. The Young’s modulus and the damping property of the ceramic coating, derived from the impulse excitation technique, are investigated as a function of the temperature up to 1000°C.

Abstract: Strategies for time-economic lifetime assessment of thermal barrier coatings (TBC) in service are described and discussed on the basis of experimental results, achieved on material systems with coatings applied by electron beam physical vapour deposition. Service cycles for gas turbine blades have been simulated on specimens in thermo-mechanical fatigue tests, accelerating the fatigue processes by an increase of load frequency. Time dependent changes in the material system were imposed by a separate ageing, where the samples were pre-oxidized prior to the fatigue test. Results of thermo-mechanical fatigue tests on pre-aged and as-coated specimens gave evidence of interaction between fatigue and ageing processes. An alternative approach is used, which is focused on the evolution of a failure relevant damage parameter in the TBC system. The interfacial fracture toughness was selected as a damage parameter, since one important failure mode of TBCs is the spallation near the interface between the metal and the ceramic. Fracture mechanical experiments based on indentation methods have been evaluated for monitoring the evolution of the interfacial fracture toughness as a function of ageing time. It was found that the test results were influenced by both changes of the interface (which is critical in service) and changes in the surrounding material.

Abstract: This paper gives a short overview of tests applied for the investigation of long term behaviour of thermal barrier coating systems. A variety of tests has been conducted on an exemplary material system with the coatings applied by electron beam physical vapour deposition. Damages and damage evolution in different tests are compared. Since the observed damage mechanisms are different, it is proposed to design laboratory tests as realistic as possible, especially if the test data are used for lifetime assessment. In order to get reasonable testing times, the damage accumulation has to be described as a function of loading history, long time before failure. For the case of final failure by spallation of the ceramic top coat, it is proposed to use the apparent interfacial fracture toughness as damage parameter. Several methods for measuring the apparent fracture toughness of brittle coatings are discussed with respect to their application to thermal barrier coating systems.

Abstract: The basic requirement for the use of a ceramic coating is sufficient adhesion to its substrate. A measure of the adhesive properties of a coating is the interfacial fracture toughness. The test method applicable for interfacial fracture toughness measurements depends on the mechanical properties of the material system and the geometry of the test piece. In this work, indentation methods have been evaluated for the estimation of the fracture toughness of ceramic thermal barrier coatings on metallic substrates. Coatings of 100 to 300 µm thickness were applied by electron beam – physical vapour deposition. The performed test types were Vickers indentation at the interface of polished cross sections of the coating system and Rockwell indentation with a brale C indenter, penetrating the coating perpendicular to the surface. Both tests generate delamination, in which the delamination crack length corresponds to the interfacial fracture toughness. Fracture surfaces and cross sections of the fractured coatings were investigated by optical and scanning electron microscope. Determined fracture toughness values are discussed with respect to the loading conditions in the test and the fracture process – i.e. interaction between indenter and coating system and the crack propagation path.