Papers by Author: D. Minić

Abstract: In this work we investigated the interaction of ns laser pulses (TEA CO2 and Nd:YAG) with a titanium nitride (TiN) thin film. The TiN thin film of 1μm thickness was deposited by PVD method on silicon substrate. Modification of TiN film was induced by laser pulses with power densities of about 108 and 109 W/cm2. Part of the laser energy absorbed on the target surface was converted into thermal energy and effects such as melting, vaporization and exfoliation were observed. Nd:YAG laser produced craters with sharp periphery, while TEA CO2 laser created damages with broad boundary zone. Hydrodynamic effects were especially pronounced during irradiation with TEA CO2 laser.

Abstract: Thermal stability of neutral Zn(II), Pd(II) and Pt(II) complexes of formulae [Zn(apsox)2]·3H2O and [M(apsox)Cl] (M=Pd(II), Pt(II), HL=(E)-2-oxo-2-{N ’-[1-(pyridin-2- yl)ethylidene]hydrazino}acetamide) were studied. The results of DSC and TG analyses within the temperature range from 20 to 600 °C in nitrogen atmosphere showed that the loss of crystal water represents the first step during decomposition of the octahedral Zn(II) complex followed by structural rearrangement of its anhydrous form. After that the complex remained stable to about 330 °C. Different from neutral square-planar Pd(II) and Pt(II) complexes, a satisfactory resolution of the peaks in DSC of the Zn(II) complex enabled determination of the activation energies of its structural transformation and thermal degradation.

Abstract: The thermogravimetric analysis of superabsorbing polyacrylic hydrogel dehydration, performed under non-isothermal conditions at different heating rates was discussed. Particularly, the influence of the heating rate on the obtained results is given in detail. For this purpose the Weibull distribution function was applied. The thermogravimetric curve when the heating rate tends to zero was evaluated. The activation energy E = 63 kJ/mol, pre-exponential factor A = 2.97 × 108 min−1, and rate constant k = 2.76 × 10−3 min−1 were determined on the basis of this curve.