Papers by Author: Dacian Tomus

Abstract: Plate samples of Al-2Sc were processed with an electron beam (EB) gun in a vacuum of 10-3 Pa at 50kV and 30 µA. EB processing suppressed the formation of primary Al3Sc, altered the morphology of the eutectic (Al)-Al3Sc, and increased the solubility of Sc in the eutectic (Al). In addition, its cyclic heating effect induced the precipitation of Al3Sc. EB processing resulted in more profound hardening than conventional high temperature solid solution and ageing.

Abstract: Electron beam (EB) direct manufacturing is an additive near-net shape digital fabrication process developed recently. The process offers a promising route for the fabrication of intricate speciality aluminium alloy parts for aircraft and aerospace applications because of the excellent energy coupling between an electron beam and aluminium. As part of a fundamental study on EB manufacturing of Al alloys, this work investigates the effect of the EB processing parameters on the development of the molten pool and the solidification characteristics of Al 2219 and Al 6061 alloys. The samples were processed using a 50kV electron beam gun over a wide range of beam currents (10-40mA) and welding speeds (0.3-0.86m/min) in both the static and oscillation focus modes. In the static focus mode, the molten pool is wedge-shaped; while in the oscillation focus mode, the molten pool is hemispherical, wider and shallower. In both cases, the depth and width of the molten pool increase with increasing beam current but they are less affected by the moving speed of the EB gun in the range 0.3-0.86m/min. Electron beam re-melted and subsequently re-solidified Al 2219 and Al 6061 alloys show microstructural features distinct from those obtained under sand casting and direct chill casting conditions. In particular, fine intermetallic precipitates in the size range 100-200nm are prominent in the equiaxed grains formed in the re-solidified weld beads of Al 6061 compared to the coarse intermetallic particles up to 10m in size prior to EB processing. EB processing offers opportunities for aluminium alloy development.

Abstract: The range of commercial titanium alloys available is currently extremely restricted, with one alloy (Ti-6Al-4V), and derivatives of it, accounting for a very large proportion of all applications. High performance alloys are costly to fabricate and limited to low-volume applications that can sustain the cost. With the emergence of new processing technologies that promise to reduce significantly the cost of production of titanium metal, especially in powder form, there is an emerging imperative for cost-effective near net shape powder processing techniques to permit the benefit of reduced metal cost to be passed on to higher-volume applications. Equally, there is a need for the design and development of new alloys that are intrinsically low-cost and lend themselves to fabrication by novel cost-effective net shape processing. The approaches that might be used to select, design and process both conventional alloys and novel alloy systems will be reviewed, with a focus on innovation in design of low-cost alloys amenable to new processing paths and increasingly tolerant of variability in composition.

Abstract: Powder metallurgy is widely used to produce alloys with low cost of production. The main drawback using powders is the level of residual porosity of final product which often implies the application of a complicated and costly hot isostatic pressing process. However, this issue can be overcome by using equal channel angular pressing (ECAE) with back pressure (BP). The use of severe shear deformation, with imposed hydrostatic pressure, allows a reduction in the range of compaction temperatures compare to those used in conventional practice. The compaction of Ti-6Al-4V powder by the ECAE method has been investigated. The compaction has been performed at temperatures starting from room temperature (RT) and increasing up to 400°C with various back pressures ranging from 0 to 350MPa. A billet processed by ECAE with 43MPa back-pressure at 400°C was found to have improved relative density of 97.5% and increased Vickers hardness of 369HV, compared to values of 96.7% and 325HV respectively obtained at RT. A relative density of 98.2% and 426HV hardness were measured for billets processed with BP = 262MPa at 400°C. A fully compact billet was obtained by applying 350 MPa of BP at 400°C.

Abstract: Thermal- and stress-induced martensitic transformation was investigated on TiNi shape memory alloys subjected to severe plastic deformation (SPD) by cold rolling. TEM observation revelaed the sample is a mixture of nanocrystalline and amorphous after 40% cold rolling. DSC analysis suggested that the martensitic transformation was suppressed when the thickness reduction was over 25% reduction. Aging at lower temperatures (573 ~ 673 K, 3.6 ks) restores the phase transformations, but to a limited extent. The stress-strain curves of nanocrystalline/amorphous TiNi are characterized by absence of stress-plateau and small hysteresis.

Abstract: Using the ultrafine laminate method, thin foils (50 µm) of Ni-rich TiNi shape memory alloys were produced. Overall composition of the Ti/Ni laminate is Ti-50.7%Ni. TiNi (B2) phase was obtained after different diffusion treatments at 1073 K for 36 ks. Aging treatment at 773 K for 3.6, 18, 36, 72 and 144 ks were also performed. Phase transformation behavior of aged foils changed from two-step, to three-step and then to two-step transformation, which is similar to the case of bulk TiNi alloys. Uniform distribution of Ti3Ni4 phase was observed for aged samples by transmission electron microscopy. Two-way shape memory effect of the aged TiNi foil was also demonstrated.