Papers by Author: Guillermo Monrós

Abstract: In this communication we provide some examples of hot research topics in the field of ceramic pigments. The more classical approach of finding new host lattices or chromophores is first illustrated with recent examples of new formulations for yellow-orange, reddish-brown and blue ceramic pigments based on pseudobrookites and related titanates. Then we highlight the advantages of using non-conventional preparation routes, which can provide different pigmenting alternatives for the emerging ink-jet printing technology, such as the development of nanoor sub-micron pigments and “ceramic inks”, or the use of appropriate precursors for in situ-generating pigments.

Abstract: synthesis and characterization of a new chromium- calcium titanate red ceramic pigment is described in this communication. The pigment is based on the solid solution of chromium (IV) in calcium titanate and was characterized as red-brown pigment in a CaO-ZnO-SiO2 transparent glaze used for ceramic tiles (1080°C). XRD, UV-Vis-NIR spectroscopy and CIE-L*a*b* techniques of characterization have been employed. The L*a*b* valour of the optimal pigment with 0,015 mol/mol of chromium fired at 1100°C with a soaking time of 3 hours and 5% weight added to the transparent glaze is 59.3/12.5/9.5. Likewise 5%w. addition of NHCl used as flux agent increase b* and decrease L* valour (L*a*b*=45.2/15.3/5.3).

Abstract: Research on new ceramic dyes is addressed to obtain best pigmenting materials in order to reach higher thermal stability (e.g. for porcelainised stoneware) than classical pigments, higher chemical stability towards the coloured matrix or low toxicity in order to satisfy health and environmental requirements. The earlier developments on the research in new ceramic pigments based on new crystal structures (e.g. perovskite, hexaaluminates, fergusonite, pseudobrookite …), new chromophores (e.g. ruthenium, bismuth and rare earth ions), or new methods of preparation are discussed in this communication.