Papers by Author: Jian Liang Shen

Abstract: The uniform distribution and the stability of the substrate temperature are the most important factors that deeply affect the quality and the growth rate of diamond films. In this paper, cemented carbide cutters were chosen for substrates, the 3D finite element (FE) model of filaments and substrates was developed in ANSYS 8.0, the calculated results show that the substrate temperature is influenced by the filament temperature, filaments diameter, the quantity of the filaments and the distance between the filaments and the substrates. The 3D finite element model of filaments and substrates also provides a basis for selecting the parameters to obtain uniform diamond films in miniature EACVD system.

Abstract: Mechano-chemical modification (MCM) of nanodiamond was conducted with a stirring mill. A new type of silane coupling agent, GW was chosen as its modifier. X-ray photoelectron spectroscopy (XPS) and Fourier transform infrared (FT-IR) were employed to study the surface properties of nanodiamond before and after treatments. Results showed that the peaks related to GW and the ball (for example, Fe, Si and Cl) appeared obviously after its MCM on their XPS spectra and mostly disappeared after its further purification with acid X or Y. A new peak located at 1382.48cm-1 was very strong after further purification. It was proven by their FT-IR spectra.

Abstract: A stirring mill, an ultrasonic bath and a high-speed shearing emulsifier were adopted to modify the surface characteristics of nanodiamond (ND) respectively. The ζ-potential, size distribution and Fourier transform infrared spectroscopy (FT-IR) of ND were measured to evaluate its properties. Results show that the ζ-potential of ND modified with SHP (either by Mechano-chemical Modification or Ultrasonic measurement) drops sharply. Results also show that the rotating speed of the emulsifier exerts little influence on the size D5 but great influence on the size D95 of ND.