Papers by Author: John F. Grandfield

Abstract: Producing low-dross ingots has been a long-term goal in aluminium cast houses. The patented CASTfill technology [1] is a low-dross and high-productivity pouring system developed to fulfil this demand. This paper describes the research methods used during the development of CASTfill; now in service at Boyne Smelters Limited (BSL) since August 2009. The importance of combining scientific modelling and testing procedures with process operability, maintainability and durability to ensure the success of new technology in a production facility is also highlighted. Ingot assessments showed that the latest CASTfill design greatly reduced dross generated during mould filling. Improved ingot packaging and reduced variation of ingot weights were also observed as the results of a more tranquil flow of molten aluminium through CASTfill and its uniquely modular design.

Abstract: Control of impurity elements in Al-based alloys is of increasing technological importance, both in primary and secondary alloy production. In primary alloy production, Ni and V concentrations in the coke are rising and this is increasing the level of impurities in the final products to the extent that they are out of specification. Impurity control is also of concern in recycling due to the pickup of elements such as Fe from contaminants in the scrap, which can detrimentally affect the alloy properties. Dissolved elemental impurities can be removed by a number of different processes including boron treatment for some of the transition metals. Other processes in the cast shop for removing impurities and inclusions from Al melts include fluxing, floatation, and filtration. Gas purging, vacuum treatment, filtration, the use of salts, and combinations of these presently find commercial applications. Ultra purity Al and its alloys can be obtained using zone refining and three-layer electrolysis methods. The demand for higher purity Al has been largely met by additional electrolytic refining processes. This paper reviews the tools that are currently available to the casthouse for removing impurities and inclusions from Al melts and suggests approaches that may be useful to meet future challenges.

Abstract: Wire rod is produced by hot-rolling a bar of metal coming from a wheel/belt continuous casting process. This kind of process, e.g. Properzi, is an elaborate process in which the molten metal is poured in a cooled rotating mould formed by the groove of a wheel and closed by a belt. In order to better understand the heat transfer phenomenon and solidified bar characteristics, depending on process parameters a three dimensional thermo-mechanical model has been developed. The model, based on the finite-element method, calculates the heat transfer coefficient of the air gap at the metal-mould interface as a function of the size of the gap determined by the bar contraction and wheel and belt thermal deformations. The air gap formation due to metal shrinkage and mould deformation is the main factor which determines the heat extraction. Wheel temperature measurements with thermocouple and belt temperature measurements with an infrared system were carried out to verify model results. Attempts were also made to measure a liquid pool profile using doping with copper rich alloy. The model shows the effect of the casting temperature and the rotation speed on the air gap formation and resulting temperature and stress fields. The model can be applied to issues such as maximising wheel and belt life and minimising solidification defects.

Abstract: Tomago Aluminium experienced problems with the boiling of cooling water in ingot casting machines, where water splashed onto molten aluminium after mould filling. The boiling problem was particularly severe when new standard moulds were installed. This paper describes the experiments and modelling employed to analyse and identify the cause of the problem and based on the results, modifications to mould geometry were suggested. Subsequent testing in lab and field trials showed that the boiling was suppressed. The first set of modified moulds in service at Tomago Aluminium showed mould life was improved as predicted. Other issues with the modified mould design, which arose in service, are also discussed.

Abstract: Management of inclusions is an important part of quality control within the aluminium cast house. Inclusions have a detrimental effect on many aluminium cast products. The ability to reliably detect inclusions in a timely fashion is an essential part of this process. There are a number of tools available for inclusion measurement based on different principles. Techniques for inclusion detection such as metallurgical analysis, K-Mold, Podfa, Lais, Prefil all have a delay before detailed results are available. Ultrasound provides a possible technique for an online sensor, however has not as yet managed sufficient sensitivity. LiMCA, based on the Electrical Sensing Zone, has provided the most sensitive online detection to date, but other electromagnetic techniques such as a multiple voltage array sensor offer promise of a sensor which can be built for lower cost and can sample a larger portion of the melt.

Abstract: The technology for controlling smelter metal impurities post reduction has steadily improved. For example, control of sodium has seen the reduction and, in some plants, the elimination of chlorine gas from the casthouse. However, changes in the purity of cell feed materials such as anodes are giving rise to new challenges in impurity control; vanadium and nickel levels are an emerging problem. This paper briefly reviews the important impurities and their effects on downstream casting, forming and final application properties. Particular emphasis is given to nickel and vanadium. Strategies for controlling these impurities are also discussed and areas where new technology is needed are also highlighted. In some cases it is not known what the tolerable limits of impurities are. There are a plethora of metal refining techniques used in the extraction of other metals which could be investigated for the control of impurities in smelter grade aluminium.

Abstract: The aluminium industry is reducing its carbon dioxide emissions and environmental footprint. In order to identify and prioritise areas in the cast house where greenhouse gas emissions can be reduced it is necessary to quantify CO2e (CO2 equivalent tonnes) emissions for the various cast house operations. In this study two typical cast house layouts are examined. In one case, 22kg 99.85% aluminium remelt ingots are produced using chain conveyor ingot casting machines. In the second case, wrought alloy extrusion and rolling slab direct chill cast products are made. Both plants are sized at 500ktpa. The various process inputs in terms of energy and materials were identified and typical usage rates assigned. The results show that general electricity consumption, dross generation and furnace energy consumption are the three biggest areas of CO2e and should be targeted for improvement. Magnesium consumption also has a large effect in the case of the

Abstract: Using modifications to the Rappaz-Drezet-Gremaud hot tearing model, and using empirical equations developed for grain size and dendrite arm spacing (DAS) on the addition of grain refiner for a range of cooling rates, the effect of grain refinement and cooling rate on hot tearing susceptibility has been analysed. It was found that grain refinement decreased the grain size and made the grain morphology more globular. Therefore refining the grain size of an equiaxed dendritic grain decreased the hot tearing susceptibility. However, when the alloy was grain refined such that globular grain morphologies where obtained, further grain refinement increased the hot tearing susceptibility. Increasing the cooling decreased the grain size and made the grain morphology more dendritic and therefore increased the likelihood of hot tearing. The effect was particularly strong for equiaxed dendritic grain morphologies; hence grain refinement is increasingly important at high cooling rates to obtain more globular grain morphologies to reduce the hot tearing susceptibility.