Papers by Author: Krystian Prusik

Abstract: The morphology and magnetic properties of the Ho(Ni_0.8Co_0.2)_­3 crystalline and ball – milled intermetallic compounds are presented. The polycrystalline bulk compound crystallizes in the rhombohedral PuNi₃ - type of crystal structure and indicates ferrimagnetic arrangement with the Curie temperature of T_C = 48 ± 1 K, the helimagnetic temperature T_h = 26 ± 2 K with the total saturation magnetic moment of 7.78 µ_B/f.u. at 2 K. The use of the HEBM method leads to the formation of nanoflakes with typical thickness of less than 100 nm. The extended milling leads to the reduction in particles/crystallites size and in the emergence of the relatively small coercivity (H_C).

Abstract: The aim of this study was to analyze the influence of the method of preparing the substrates in the form of simple oxides for the structure of the final Bi₅Ti₃FeO₁₅ ceramics. Milling of the substrates was carried out by two methods: the classical one by hand mixing in a porcelain mortar, and by high-energy. Structure studies were performed by the X-ray diffraction (XRD) method. XRD patterns were analyzed with the Rietveld method using the DBWS 9807a program. It was found out that the slightest deviation of the network parameters from the catalog data occurs for the sample obtained from simple oxides by free sintering (BTFs). Furthermore, it was also determined that the optimal high-energy time of the substrates is 5 hours. When compared to the ICDD catalog data, the resulting ceramics is a single phase one and has the lowest network parameters deviation among all samples which were subject to high-energy.

Abstract: In the present study the series of the Ni46.2Co5.0Mn36.1In12.6, Ni48.7Co5.2Mn34.4In11.6 and Ni45.6Co4.8Mn36.4In13.2 alloys (at. %) were studied. The influence of the indium addition on structure and phase transitions was studied. All alloys were annealed at 900°C for 24 hours and then slowly cooled in the furnace. After annealing all of the studied alloys showed the macrostructure of radially oriented columnar grains, which lied in the direction perpendicular to the casting axis. For the alloy containing about 13 at. % of indium the monoclinic 14M modulated martensite was stated at room temperature. Apart from the modulated martensite in a1_133 alloy the gamma phase was also observed. For alloy with higher indium content the mixture of cubic L21 parent phase and cubic gamma phase was identified. All studied alloys showed one-step martensitic transformation.

Abstract: Two Ni-based (Ni-Mn-Ga and Ni-Mn-Co-In) ferromagnetic nonstoichiometric shape memory alloys were studied in order to determine the influence of hot extrusion process on macro, microstructure and texture of the studied alloys. The microstructure of the alloys in the as cast state and after extrusion was analyzed by electron backscatter diffraction technique. Typical microstructure of the as cast alloys consisted of radially oriented columnar grains elongated perpendicularly to the casting axis. For the alloys Ni-Mn-Ga and Ni-Mn-Co-In alloys the 10M and 14M modulated martensite were observed, respectively. After extrusion Ni-Mn-Ga samples revealed high density of fibre texture parallel to the extrusion axis. In spite of applying different extrusion parameters it was not possible to avoid cracks and overcome the brittleness of the Ni-Mn-Co-In alloys.

Abstract: In the paper Gd+Ni nanoparticles were obtained using chemical reaction of Gd nanopowder in the bath based on C4H6O4Ni (pH=7) at temperature 323 K. TEM examinations show Gd+Ni nanoparticles (about 200 nm) covered by GdF3 intermediate layer and Ni-P final layer Magnetization vs. temperature (5-320 K) show the Curie point of Gd at 290 K and at low temperature a paramagnetic component related to GdF3. The obtained Gd+Ni nanopowder of 200 nm in diameter can be used in future application without fear of oxidation.

Abstract: The aim of the work was to investigate the influence of the processing on the final microstructure of the melt-spun Ni-Fe-P ribbons. The melt-spinning was carried out in two ways. For the first one the alloy was molten in a simple single-chamber crucible and for the second one double-chamber crucible was used. The chemical composition of the alloy molten in the single chamber was Ni40Fe40P20. The two component melt-spinning was made starting from the Ni80P20 and Fe80P20 alloys. All of the three alloys were molten in titanium gettered argon atmosphere starting from 99.95 wt % Ni, 99.95 wt % Fe, Ni-P and Fe-P master alloys in the arc melting furnace. The alloys were melt-spun in helium. The phase composition and the microstructure of the melt-spun ribbons were investigated by X-ray diffraction (XRD), a transmission electron microscope (TEM), respectively. The fracture of the specimens were observed with use of scanning electron microscope (SEM). SEM observations of the fracture surfaces show different character of the fractured samples.

Abstract: In present paper two ribbons of the Ni₄₄Co₆Mn₃₆In₁₄ (at.%) were prepared under different melt-spinning technique conditions. Microstructure of the ribbons was studied by scanning electron microscopy (SEM). Depending on the liquid ejection overpressure two types of ribbons microstructures were observed. Ribbon T1 for which ejection overpressure was 1.5 bar showed typical melt-spun ribbon microstructure consisting of a top layer of small equi-axial grains and columnar grains below. For T2 ribbon (ejection overpressure 0.2 bar) only a small fraction of the columnar grains were observed. Structure analysis of the ribbons performed by XRD showed that at room temperature both ribbons have B2 parent phase superstructure. No gamma phase precipitates were observed. In order to determine the orientation of the grains the EBSD technique was applied.

Abstract: The aim of the work was to investigate the influence of silver as a modifying constituent on structure formation in Ni-P based glass forming matrix. Nickel-phosphorus-based Ni80P20, Ni78Ag2P20 and Ni76Ag4P20 alloys were prepared from 99.95 wt % Ni, 99.95 wt % Ag, and Ni-P master alloy. The alloys were melt-spun in helium. The microstructure of the melt-spun ribbons was investigated by XRD, a light microscope and a transmission electron microscope. Then the tensile tests were performed. The alloys with silver show lower tensile strength with respect to the fully amorphous Ni80P20 ribbon. The ductility of the amorphous matrix melt-spun Ni78Ag2P20 and Ni76Ag4P20 alloys was improved by addition of silver forming fcc-Ag precipitates in comparison with Ni80P20amorphous alloy. SEM observations of the fracture surfaces show different character of the fractured samples. The pattern and the number of the crack lines changes, depending on the silver content. For the fully amorphous Ni80P20 alloy simple brittle cracks are observed, however the alloys with silver content show more developed surfaces near the fractured regions and form crack lines arranged 60° with loading direction.

Abstract: Ferromagnetic shape memory alloys (FSMA) are relatively new smart materials group. Recently, new FSMA from NiMnX (X=Sb, Sn, In, Co+In) systems are considered as alternative to the well known NiMnGa alloys. Four alloys of the following compositions: Ni₄₃Mn₃₅Co₄In₁₈, Ni₄₁Mn₃₅Co₄In₂₀, Ni₄₂Mn₃₅Co₅In₁₈, Ni₄₀Mn₃₅Co₅In₂₀ were studied in order to determine microstructure, phase composition and martensitic transformation temperatures versus their chemical composition. Structure of the alloys was studied by optical and transmission electron microscopy (TEM). All of the studied alloys showed macrostructure consisting of radially oriented columnar grains in the direction perpendicular to the casting axis. The structure of the phases occurred in the studied alloys depended on the cobalt and indium content. For the alloys containing 20 at. % of In at room temperature only L2₁ parent phase was observed whereas for those containing 18 at. % of In either single phase 14M modulated martensite or mixture of 14M martensite and L2₁ parent phase were seen. DSC measurements showed in studied alloys single-state martensitic transformation. Decrease In content of 2 at.% caused about 80°C fall of martensitic transformation temperatures. Curie temperature T_c increases of 20°C with 1 at% rise of the cobalt content.

Abstract: The T24 steel belongs to a new group of bainitic steels introduced currently to the power industry. Higher requirements connected with applying higher steam parameters in power units are the reason why the low-alloy steels used so far can no longer be applied. Therefore, new T24 steel has been developed in Europe on the basis of 10CrMo9-10 (10H2M) steel, which has been used in the power industry for many years, as a result of modification in its chemical composition. This modification consisted in introducing additions and microadditions of titanium, vanadium, boron and nitrogen into the base steel. As a result of the modification the new-found T24 steel is characterized by higher mechanical properties in comparison with the base steel, which allows to use the steel for tight shields in the new supercritical power units. The material for research was low-alloy bainitic T24 steel. Samples for examination were taken from a pipe section of the following size: outside diameter 44.5mm, wall thickness 7mm. Samples were isothermally aged in the air atmosphere, at the temperature of 580°C and at times up to 12 000 hours. Changes in the microstructure were observed and recorded by means of high-resolution electron microscope, JOEL JEM 3010. Identification of the precipitates was made using carbon extraction replicas and thin foils with the SAED method. The aim of research was the analysis of precipitation processes. They are extremely important in the context of long-term service and maintaining strength parameters above the minimum level. The tests were performed on T24 steel for the as-received condition (after heat treatment) and after 12 000 hours of ageing at the temperature of 580°C. The research made it possible to determine the morphology of precipitates. It also allowed to establish the sequence of precipitation process for the examined steel.