Papers by Author: L. Vandeperre

Abstract: Electrophoresis is the effect that when an electric field is applied to a suspension of a powder in a liquid, the powder particles move under influence of this field. Frequently the powder particles also deposit at one of the electrodes. The form of the electrode determines the form of the deposit, hence shaping is possible. The current insights into the science and technology of electrophoretic deposition (EPD) will be summarized. EPD is well suited for shaping layered microstructures (laminates), by simply changing repeatedly between two or more suspensions during deposition. Tubular laminates consisting of silicon carbide layers and crack deflecting graphite interlayers have been produced. These tubes demonstrate an enhanced fracture energy and a gradual mode of failure. Another area of advanced ceramics where the use of EPD makes sense are functionally graded materials (FGM) in which one tries to combine in one component high hardness and high toughness. EPD allows the formation of FGM by depositing from a powder suspension to which a second suspension is continuously added during the process. An example will be shown of a graded WC-Co hardmetal.

Abstract: Electrophoresis is the effect that when an electric field is applied to a suspension of a powder in a liquid, the powder particles move under influence of this field. Frequently the powder particles also deposit at one of the electrodes. The form of the electrode determines the form of the deposit, hence shaping is possible. The current insights into the science and technology of electrophoretic deposition (EPD) will be summarized. EPD is well suited for shaping layered microstructures (laminates), by simply changing repeatedly between two or more suspensions during deposition. Tubular laminates consisting of silicon carbide layers and crack deflecting graphite interlayers have been produced. These tubes demonstrate an enhanced fracture energy and a gradual mode of failure. Another area of advanced ceramics where the use of EPD makes sense are functionally graded materials (FGM) in which one tries to combine in one component high hardness and high toughness. EPD allows the formation of FGM by depositing from a powder suspension to which a second suspension is continuously added during the process. An example will be shown of a graded WC-Co hardmetal.

Abstract: The aim of this paper is to study the effect of relaxing the assumption in the Peierls analysis that the dislocation must be wide compared to the atom spacing. To do this the use of the continuum description of the in-plane strains caused by the presence of an edge dislocation is replaced by an atomistic interaction taken to be linear elastic. It is found that in this case the inplane interactions give a contribution to the overall misfit energy changes that are not present in the Peierls analysis because of the use of a continuum approach. This contribution modifies these energy changes so that the total misfit energy is a minimum at the conventional low energy positions (whereas in the Peierls analysis it is a maximum) and gives values of the Peierls stress in reasonable agreement with those measured.

Abstract: The correlation between hardness, H, and yield strength, Y, for hard materials is reexamined using an analytical approach to provide a physical interpretation, which explains the trends observed. Existing analytical predictions using the analogy of the spherical cavity fail to reproduce experimental and finite element results because the accommodation of the intrusion of the indenter due to surface deformation is not taken into account, while experiments made here and elsewhere indicate that the latter can be substantial. A simple modification is proposed, which accounts for this, and allows for a reasonable prediction of the relation between hardness and yield strength for materials, which have a well determined yield point and do not strain harden. The treatment also allows explaining the effect of indenter geometry on measured hardness for such materials.