Papers by Author: Mark Robertson

Abstract: An SOFC must have sufficient mechanical strength and interface adhesion to ensure it can be handled without breakage during fabrication and assembly, and has desired performance and reliability. Methods for measuring mechanical properties and interface adhesion of an SOFC have been developed and measurements made on a cermet-supported SOFC with a SDC electrolyte. The SOFC evaluated had a porous NiO-YSZ substrate, a porous NiO-SDC anode and a dense SDC electrolyte fabricated using tape-casting, screen-printing and co-firing techniques. The flexural strength and interface adhesion of the substrate, the anode and the electrolyte, along with their Young’s modulus, hardness and residual stress, were quantitatively measured. The results of the measurements indicate that the NiO-YSZ supported, SDC electrolyte SOFC has adequate mechanical strength and sufficient interface adhesion.

Abstract: In this study, an addition of Co and Cu oxides to Sm0.2Ce0.8O1.9 (SDC) was studied to improve the SDC sinterability. It has been found that both Co and Cu oxide are very effective as sintering aids, and the SDC sintering temperature can be reduced from 1400°C without aids to below 1000°C with only 1at.% of either Cu or Co. As compared to the pure SDC, a slight decrease of ionic conductivity was observed in SDC with Cu sintering aid. There is no obvious effect on electrochemical property of SDC with Co sintering aid under 2.5at.%.