Authors: Wei Zhang, Fu Sheng Pan, Ming Bo Yang, Jin Zhang, Tao Wen
Abstract: Silane treatment is an effective method of chemical conversion as a replacement for chromium treatments. In this paper, KH-550 silane treatment was adopted to improve the corrosion resistance AZ31 magnesium alloy. Hydrolysis process of KH-550 in the silane solutions was detected by the conductivity detection method. It was found that KH-550 silane could be hydrolyzed easily and its hydrolysis time was about 10 minutes. Polarization curve and salt immersion were carried out to investigate the corrosion behavior of the coated magnesium alloy treated by five kinds of silane solutions with different silane concentrations. When the concentration of KH-550 in the silane solution was 8%, the coated specimens by heating at 100°C for half an hour after the surfaces dry had more excellent corrosion resistance than others. It was shown that the KH-550 silane treatment could form a -Si-O-M covalent bonded film/metal interface and -Si-O-Si siloxane chains to improve the corrosion resistance of coated magnesium alloy.
927
Authors: Jia Shen, Ming Bo Yang, Fu Sheng Pan, Ren Ju Cheng
Abstract: The as-cast microstructures and mechanical properties of Mg-3Ce-1.2Mn-0.9Sc and Mg-3Ce-1.2Mn-1Zn magnesium alloys were investigated and compared. The results indicate that the as-cast microstructure of Mg-3Ce-1.2Mn-0.9Sc alloy was mainly composed of -Mg, Mg12Ce and Mn2Sc phases, and that the as-cast microstructure of Mg-3Ce-1.2Mn-1Zn alloy was mainly composed of -Mg, Mg12Ce and MgZn phases. In addition, the as-cast tensile and creep properties of Mg-3Ce-1.2Mn-0.9Sc alloy were higher than that of the Mg-3Ce-1.2Mn-1Zn alloy. The difference of the two alloys in as-cast tensile and creep properties may be related to the initial microstructures of the two alloys.
746
Authors: Ming Bo Yang, Li Wen Tang, H. Yang, Wei Lin Zhao
Abstract: In the paper the microstructure and properties of surface coating for Cr12MoV steel
treated by TD (Thermal Diffusion) salt-bath vanadizing process are investigated. The research
results indicate that after treated by the TD salt-bath vanadizing at 1223K for 5h and followed by oil
quenching, and aged at 453K for 2h, the Cr12MoV steel could obtain a surface coating whose
thickness is about 11.4um. The coating is mainly composed of vanadium carbide, and its thickness
and microstructure are uniform and compact, respectively. At the same time, the coating obtained
exhibits super-high surface microhardness, 2586HV. Then the wear resistance property of
Cr12MoV steel is improved drastically. In addition, the research results reveal that the effect of TD
salt-bath vanadizing treatment on the surface roughness of Cr12MoV steel is not obvious.
196
Authors: Yan Long Ma, Fu Sheng Pan, Ming Bo Yang
Abstract: The effects of different solid solution and aging technologies on the microstructure of
AM50 were studied. The results indicated that heat-resistant Al-Mn phases were the major second
phases in AM50 alloy under all testing conditions. Highest microhardnesses were obtained not only in
as-aged sample but in as-solution treated sample, which indicated that the strengthening mechanism
for AM50 alloy was not limited to precipitation reinforcement.
103
Authors: Fu Sheng Pan, Ming Bo Yang, Yan Long Ma
Abstract: The latest research results on new types of magnesium alloys containing strontium or rare
earth elements are reviewed. Special attentions are paid to the alloying design, microstructure and
properties controlling, the influence of minor addition of Sr and RE on the microstructure and
properties of existing magnesium alloys. Some new types of magnesium alloys containing Sr or RE
are introduced and discussed.
191
Authors: Ming Bo Yang, Fu Sheng Pan, Yan Long Ma, Li Wen Tang
Abstract: In this paper, the effects of Sb and RE on the solutionized microstructure and
microhardness of Mg-6A1-1Zn-0.7Si magnesium alloy are investigated. The research results indicate
that the solid solution treatment can result to the modification of Chinese script shaped Mg2Si phases
in the microstructure of experimental alloy, and adding small amounts of RE and Sb can strengthen
the modification efficiency. In addition, after the solid solution treatment at 420°C, the
Mg-6A1-1Zn-0.7Si alloy added 0.4%Sb and 0.25%RE exhibits higher microhardness, but the effect
of Sb and RE additions on the changing law between microhardness and solutionized time, is not
obvious.
135
Authors: Yan Long Ma, Fu Sheng Pan, Ru Lin Zuo, Jin Zhang, Ming Bo Yang
Abstract: In the present paper, nine kinds of alloys with different contents of zinc and zirconium were
cast and the influence of zinc and zirconium individually and jointly on the microstructure of the ZK
alloys were investigated. The results indicated that the shape and amount of the eutectic were closely
related to the content of Zn. With the increase of Zn content, the eutectic was prone to have
fish-bone-like shape. When the eutectic grew up to contact with each other, then network eutectic
formed; Zr could intensively refine not only the grain size but also the eutectic, but when Zr>0.6%,
compound containing Zr or pure Zr granules would appear. That the increase of the Zn must go with
the increase of the Zr proved the combined influence of the two alloy elements.
369
Authors: Ming Bo Yang, Fu Sheng Pan, Liang Bai, Ren Ju Cheng
Abstract: The effects of the Al content on the as-cast microstructure and mechanical properties of
Mg-xAl-0.7Si based magnesium alloys which contained 1%Zn, 0.25%Mn, 0.4%Sb and 0.25%RE
were investigated by optical microscopy(OM), scanning electron microscopy(SEM), X-ray
diffraction(XRD) analysis and tensile testing. The results indicated that the effects of the Al content
from 6% to 8% on the alloy phase types of the experimental alloys were not obvious, and the as-cast
microstructure of the experimental alloys with different Al content were composed mainly of the
α-Mg matrix, Mg17Al12 phase, Mg2Si phase and Mg3Sb2 phase. The Chinese script morphology of the
Mg2Si phase was very obvious in the experimental alloy with 6%Al. With the increase of Al content
from 6% to 8%, the yield strength of the experimental Mg-xA1-0.7Si based alloys at room
temperature increased, but the yield strength of the experimental Mg-xA1-0.7Si based alloys at 150
°C decreased.
191
Authors: Ren Ju Cheng, Aitao Tang, Ming Bo Yang, Fu Sheng Pan
Abstract: The influence of Al-10.5%Sr master alloy, which is much cheaper than Mg-Sr master
alloys, on the as-cast microstructure of the AZ31 alloy was investigated. The research results revealed
that the Al-10.5%Sr master alloy produced obvious modification of the as-cast microstructure of the
AZ31 alloy, and the modification efficiency increased with the holding time from 0min to 60min and
the amount of Sr from 0.01% to 0.1%. Moreover, the results also showed that the Al-10.5%Sr master
alloys of different states had different modification efficiency on the as-cast microstructure of the
AZ31 alloy. The Al-10.5%Sr master alloys in extrusion deformation state and rapid solidification
state had better modification efficiency than the Al-10.5%Sr master alloys received and in heat
treatment state, which could be related to the microstructure of the Al-10.5%Sr master alloys with
different states.
183
Authors: Ming Bo Yang, Fu Sheng Pan, Li Wen Tang, Hong Jun Hu
Abstract: The semi-solid compression deformation behavior of the AZ91D alloy with non-dendritic
structure, which was obtained under the semi-solid isothermal treatment condition of 570°C×60min,
was studied by means of Gleeble-1500 thermal-mechanical simulator. When the compression strain
was lower than 0.7, along with the compression strain increasing, the compression stress firstly
increased rapidly, then decreased rapidly, and finally kept a constant stress level gradually. Under the
condition of different deformation temperatures and deformation rates, the maximum compression
stress was obtained simultaneously when the compression strain value was 0.025 approximatively.
Furthermore, when the deformation rate kept a constant, the compression stress decreased along with
the deformation temperature increasing, and when the deformation temperature kept a constant, the
compression stress increased along with the deformation rate increasing.
151