Papers by Author: Pil Ryung Cha

Abstract: In this presentation, a novel phase field grain growth model combined with a micro-elasticity effect including elastic anisotropy and inhomogeity is presented to demonstrate the effect of micro-elasticity on grain growth and texture evolution. We report on texture evolution and abnormal grain growth induced by external elastic load from the viewpoint of micro-elasticity and first demonstrate that the previous mechanism (macroscopic viewpoint) on the effect of external elastic load on grain growth does not work in strain-controlled system. In contrast to the macro-elastic descriptions, strong localization of strain energy density and inhomogeneous distribution even inside grains are observed. Moreover, elastically soft grains with a higher strain energy density grow at the expense of the elastically hard grains to reduce the total strain energy. It is observed that strong <100>//ND fiber texture was developed in poly-crystalline Cu with initial random texture by biaxial external strain while <111>//ND fiber texture evolved in biaxial external stress condition. Even, grain growth of <100>//ND textured grains is occurred as abnormal grain growth when <100>//ND textured grains are surrounded by <111>//ND fiber textured grains.

Abstract: Phase-field model (PFM) in multiple orientation fields was used to simulate the grain growth in three-dimensions (3-D) for isotropic and anisotropic grain boundary energy. In the simulation, the polycrystalline microstructure was described by a set of non-conserved order parameters and each order parameter describes each orientation of grains. For isotropic grain boundary energy, the simulation showed the microstructure evolution of normal grain growth. For anisotropic grain boundary energy, however, the simulation showed that certain grains which share a high fraction of low energy grain boundaries with other grains have a high probability to grow by wetting along triple junctions and can grow abnormally with a growth advantage of solid-state wetting. The PFM simulation shows the realistic microstructural evolution of island and peninsular grains during abnormal grain growth by solid-state wetting.

Abstract: Abnormal grain growth (AGG) takes place in many metallic systems especially after recrystallization of deformed polycrystals. A famous example of AGG in metallic system is the Goss texture in Fe-3%Si steel. During high temperature annealing of Fe-3%Si sheet, a few near Goss {110} <001> grains grow exclusively fast and consume the matrix grains. Therefore, the grains which have near Goss orientation have special advantage over other grains. As a new approach to the growth advantage of AGG, we suggested the solid-state wetting mechanism, where a grain wets or penetrates the grain boundary or the triple junction of its neighboring grains. The solid-state wetting mechanism for the evolution of the Goss texture in Fe-3%Si steel was studied experimentally and by phase-field model (PFM) simulation.

Abstract: Developments of tetrahedral amorphous carbon (ta-C) films having low residual compressive stress are essential to extend the applicability of the films. The annealing of the ta-C films was known to be an effective way for the reduction the stress of the films. However, the effects of annealing on the atomic structure of ta-C films have not been fully understood. The atomic structure changes by the annealing were studied using molecular dynamics simulation. The simulation showed that the annealing caused an increase of the atomic volume of ta-C film, which explained the stress reduction partially. However, the tendency of the stress reduction was different to high and low stress films. The annealing substantially reduced the stresses of high stress films compared to those of low stress films. Atomic structure analysis showed that the reason for the asymmetric stress reduction resulted from the relaxation of highly distorted bonds that existed in as-deposited films.

Abstract: We present a phase field model for coherent phase transition and its application to the self-assembled arrangement of second phase particles in coherent phase transition. The model developed here is free from the interface instability due to the contribution of chemical free energy and correctly describes elastically inhomogeneous system. It is observed that coherent misfit strain and anisotropy of elastic constants induce the interface instability that brings about the particle splitting and the self-assembled alignment of second phase particles. Their arrangement to the elastically soft direction occurs only in the system where the elastic contant of the precipitates is larger than that of the matrix phase.

Abstract: We present the linear stability analysis for the epitaxial thin film growth on the vicinal surface of strained Si and the growth mode diagrams of the epitaxial growth under various operation conditions. Competition between step-step elastic interactions and the asymmetry of incorporation of adatoms from the terraces to step edge is considered. Force monopoles at steps and their interaction lead to it on the vicinal surface while kinetic asymmetry of the adatom incorporation at steps due to Ehrlich-Schwoebel barrier prevents the step bunching instability. Growth mode on the vicinal surface is determined by the competition between elastic step-step interactions and Ehrlich-Schwoebel barrier.

Abstract: A phase field model for step dynamics on vicinal surface is presented. Using this model, time dependent, collective motions of steps were investigated. Through numerical simulations, morphological step instabilities induced by ES barrier were analyzed, and it is shown that this model could interpret various phenomena during step flow growth such as step bunching and meandering.