Papers by Author: R. Sh. Razavi

Abstract: Laser surface hardening is a method used for surface modification without affecting the bulk properties of materials. Due to rapid cooling and little thermal penetration in the surface layer, a homogenous structure and little distortion are usually obtained. When a high power laser irradiates a material surface, a part of the laser energy is absorbed and conducted into the interior of the material. If the absorbed energy is high enough, the material surface will melt and even vaporizes. Consequently the temperature of the process is of promote importance to incorporate an appropriate structural layer. In this regard, a study has been carried out to implement a mathematical modeling method to control the temperature gradient, which affects on the depth of the hardened layer. The model is based on solving the heat transfer equation and such a condition by assuming that the thermo-physical properties of the material are independent of the temperature. To evaluate the application of the proposed model, laser surface hardening was carried out to AISI 1050 steel, using a 1 kW CO2 laser. It was shown that the experimental results obtained are in good agreement with the proposed model.

Abstract: The titanium alloys-especially Ti-6Al-4V- are attractive materials because of their high specific strength and low density. But these alloys have poor surface properties such as wear and corrosion resistance for many industrial applications. Laser surface nitriding technique, has been the subject of considerable interest as a means of enhancing the surface performance of titanium alloys. In the present paper, the corrosion properties of laser nitrided Ti-6Al-4V alloy that have been reported by several researchers until now is considered. The microstructure changes, phase’s formation and the influence of laser processing parameters on them, in laser nitriding layers of Ti-6Al-4V alloy are investigated in different manners like SEM, TEM, XPS and XRD. At the end of this paper, the effects of laser nitriding on the corrosion behavior of Ti-6Al-4V alloy are reviewed.

Abstract: Laser gas nitriding of Ti-6Al-4V alloy was carried out using a Nd:YAG pulsed laser under pure nitrogen environment at a flow rate of 30 l/min. The microstructure and corrosion behavior of the nitrided samples were examined using scanning electron microscopy, XRD, XPS, and anodic polarization tests in 2M HCl solution. For comparison, untreated samples were tested under the same conditions. After laser treatment, samples showed a relative flat surface with no problems of cracks or delamination of the alloyed tracks. Laser nitriding produced dendritic structures. The microstructure of the laser melted zone consisted of a thin continuous layer followed by a nearly perpendicular growth of dendrites. Below this a mixture of small dendrites and large needles with random orientation was produced. X-ray spectrum and XPS analyses from the surface of the laser nitrided specimen at different depth, confirmed that the thin top layer and large dendrites close to the surface corresponded to TiN. It can be also seen that the strong TiN peaks on the top surface gradually decrease with depth which suggests that the structure beneath the top surface is likely TiN0.3 and ά-Ti mixtures. In general, the corrosion potential of laser gas nitrided specimens was relatively nobler than the untreated sample. Furthermore, the proper laser nitrided specimen exhibited less corrosion current density, passivated more readily and also maintained a lower current density over the duration of the experiment. This was correlated with the formation of very thin, continuous TiNxOy film in an oxidation state that was confirmed by XPS analyses of the passive layers.