Papers by Author: S. Saitzek

Abstract: In the general framework of studies on nanomaterials for micro-sensors, cerium dioxide nanopowders (CeO2-z) and nanocomposites systems of copper doped ceria (CuOx-CeO2-z) were prepared and characterized. The aim of this specific study is to try to connect catalytic activity of such nanopowders with microstructure, additional phases and/or doping effect. The nanopowders of pure and doped cerium oxide were elaborated from various “Sol-Gel” chemical routes. Microstructural analysis was first carried out by X-ray diffraction (XRD). The specific areas were determined from BET adsorption techniques and the results were correlated to the size determinations obtained from XRD. The catalytic activity of such nanopowders in presence of methane gas CH4 was analyzed making use of FTIR spectrometry and a homemade device. For a better understanding of such catalytic responses, we proposed a modeling approach of solid gas interactions that takes into account a typical temperature dependent Avrami's model.

Abstract: The structural analysis of thin cerium dioxide films doped with Cu, produced by laser ablation for applications in catalytic and gas sensors, was the general aim of the study. The thin films deposited on a (100) silicon substrate were nanocrystalline structure with a well-developed texture. The morphology, as well as the preferred films orientation, is changed with the volume fraction of Cu. The observed changes affect the catalytic properties of the materials obtained which was confirmed by the catalytic tests undertaken with CH4.