Papers by Author: Severino Jackson Guedes de Lima

Abstract: This work was observed the phase formations of the mixture Al-Cu-Fe processed vial mechanical alloying, powders pressing at room temperature and subsequent heat treatment. The mixture of powders was made on the nominal composition Al65Cu20Fe15. A mill of high energy of the horizontal atrittor type was used to process the powders mixtures, in fixed time of two hours of milling. After milling, the powders were pressing in a die closed, with a diameter of about 28mm. The samples were observed by optical microscopy and analyzed X-ray diffractometry. The results obtained in this study provide a basis for setting parameters may be used as a basis for future research and possible applications.

Abstract: This work reports an investigation about the influence of the environment of milling on the characteristics of the powders and on the structure and density of sintered samples made of these powders. Mixtures of composition W-30wt%Cu were milled for 51 hours in a high energy planetary mill in dry and wet (cyclohexane) conditions. The milled powders have composite particles. The powders were pressed and sintered at 1050º, 1150º and 1200°C under flowing hydrogen. The isothermal times were 0 minutes for the first two temperatures and 60 minutes for the latter. The samples reached around 95% of relative density. The powders were characterized by means of XRD and SEM. The sintered samples were characterized by means of SEM, optical microscopy and density measurement.

Abstract: In this study Cu-13.8Al alloys with 3.0% and 4.0% (wt%) of nickel were obtained by induction melting. The effect of homogenization heat treatment and hot rolling on the transformation temperatures of these alloys was investigated by differential scanning calorimetry. It was observed that the transformation temperatures increase with long homogenization times, and also by hot rolling, and this displacement is smaller for alloys with 4.0% of nickel. In both alloys in the quenched state, the reversion reaction is characterized by the appearance of multiple peaks attributed to the presence of martensites 2H and 18R. The influence of the rolling process must be associated with the loss of Ni and Al during the process.

Abstract: Polycrystalline copper-based shape memory alloys have been of particular interest in relation to Ni-Ti because of their low cost and good shape memory effect. Nevertheless the absence of a pronounced pseudoelasticity effect restricts the number of potential applications. In this work, the influence of Nb and V on the microstructure and the mechanical properties was investigated. Samples of Cu-13.8 Al-Ni containing V and Nb alloy were prepared by induction and solution treated at 850°C and then further quenched into cold water. The addition of Nb and V promotes the formation of precipitates which act as grain refiner and subsequently improve the mechanical properties. The tensile tests were performed at temperatures slightly inferior to Mf and superior to Af, to investigate the shape recovery and pseudoelasticity, respectively. Based on the analyses of the Cu-13,8Al-2Ni-1Nb (wt%) alloy was detected rupture strains greater than 14%, besides observation of the superelasticity of these alloys and quantification of this property by means of cycling, from 0 to strains between 1 and 7%. The studies performed on alloy Cu-13.8Al- 3,5Ni-1V (wt%) made it possible to determine rupture strains in the order of 3% and its superelastic behavior through cycling for deformations between 1 and 3%.

Abstract: NiTi alloys with equiatomic composition of NiTi have the highest technological interest for its potencial application in differents areas such as biomedical, naval, aerospace, nuclear, automobilist , robotic,etc. In this work , it was used a 50Ni50Ti at % powder mixture, comercially pure, prepared by mechanical alloying in a Attritor with the following conditions: the milling speed and the ball charge were 1500 rpm and 10:1 respectively. The milling time was 2,4,8 and 16h, under an argon atmosphere at room temperature. After milling it was determined the particle size distribution, the phases by X-ray diffractions (XRD) and the powder morphology by scanning electron microscopy (SEM). The milling promotes dissolution of Titanium in Nickel and continuous amorphization by increasing the milling time. After 16h milling the alloy was almost amorphous. The powders after milling were compacted and heat treated at high temperature and microstructural evolution was characterized. In the heat treated samples were detected different phases showing heterogeneity in the alloy. The detected phases were Ni3Ti, NiTi, Ni2Ti and Ni2Ti4O. Contamination by milling was detected in the powder after milling and in the heat treated samples.

Abstract: In the present work is shown the results for solid interaction of a Cu-13.4Al-2Ni (wt%) elemental powders. Together with this mixture was placed tungsten carbide balls into a cylindrical vial under argon atmosphere. The weight ratio of the balls to powder was 20 to 1. A planetary ball mill (Fritsch Pulverizette 5) was used to perform MA at 250 rpm. The elemental powder was milled at 10min, 5 and 10 hours and a small amount of the powders were collected and analyzed via X-ray diffraction, using Cu Kα radiation (λ=0.15418 nm) and differential thermal analyses from 25 up to 450oC at a heating rate of 25oC min-1. The x-ray diffraction patterns showed that after 10h of milling the phase formation of the mechanical alloyed powders is composed of a Cu, full Cu(Al) solid solution and γAl9Cu4.