Papers by Author: Si Young Sung

Abstract: TiAl alloys Al composition range between 45 and 49 at%, includes γ-TiAl and α2-Ti3Al, are an emerging high temperature materials which has higher specific strength, oxidation ratio and specific modulus than Ni base superalloy. In this study, TiAl alloys were manufactured by plasma arc melting (PAM) and then TiAl and granular boron carbide were in-situ synthesized in PAM method again. The in-situ synthesized TiAl matrix composites were investigated by using X-ray diffractometer, optical microscope, and electron probe micro-analyzer.

Abstract: The aim of this study is to establish the net-shape forming of titanium matrix composites (TMCs) shot sleeve for Al alloys die-casting using a casting route. In-situ synthesis and casting of TMCs were carried out in a vacuum induction melting furnace. The synthesized (TiC+TiB) TMCs were examined using an scanning electron microscopy and electron probe micro-analyzer. The thermo-physical variables estimated by casting process were applied to the modeling of TMCs shot-sleeve casting using the Magmasoft®. The results of the investment casting and modeling of TMCs confirm that the casting route can be an effective approach for the economic net-shape forming of TMCs shot sleeve.

Abstract: The aim of this study is to optimize the economic net-shape forming of titanium and titanium alloys for the biomedical application. The alpha-case formation reaction between titanium, and Al2O3, ZrO2, CaO stabilized ZrO2 and ZrSiO4 mold were examined in a plasma arc melting furnace. Regardless of the thermodynamic approach, α-case formation reactions still remain to be eliminated with the complex chemical milling processes. The reason why the α-case generated cannot be explained by the conventional α-case formation mechanism. However, from the experimental results and thermodynamic consideration, it can be confirmed that the α-case is formed not only by interstitial oxygen atoms but also by substitutional metal atoms dissolved from mold materials. Based on the interstitial and substitutional α-case formation mechanism, α-case controlled net-shape forming of titanium and titanium alloys can be possible for the biomedical application.

Abstract: The aim of this study is to clarify the metal-mold reaction for the economic net-shape forming of titanium and titanium alloys. The metal-mold reactions between pure titanium, TiAl alloys and Al2O3 mold were examined in a plasma arc melting furnace. The alpha-case generation between pure titanium and Al2O3 mold could not be explained by the conventional α-case formation mechanism, which is known to be formed by the interstitials, especially oxygen dissolved from mold materials. However, based on the interstitial and substitutional α-case formation mechanism, the α-case formation between pure titanium and Al2O3 mold, and α-case free casting of TiAl alloys against Al2O3 mold can be explained. On the basis of the interstitial and substitutional α-case formation mechanism, α-case controlled net-shape forming of titanium and TiAl alloys can be possible for the structural materials.

Abstract: Over the past decades, a large number of researchers have been trying titanium alloys in an attempt to combine most of their advantages, such as high specific yield strength, good corrosion resistance, excellent fatigue property and biocompatibility by casting route. However, the wide use of titanium alloys casting has been limited, since it is considered as only a near net shape forming process in titanium alloys due to the catastrophic reactivity of molten states, the alpha-case formations and the casting defects. In order to maximize the unique property of titanium alloys casting which are comparable to wrought products and quite often superior, it is necessary to take a close examination of titanium alloys casting procedure. Therefore, the merits and demerits of various melting devices, pouring methods and mold materials will be addressed with regard to improving titanium alloys casting.

Abstract: The main purpose of this study is to evaluate the interfacial reaction between titanium matrix composites (TMCs) and A380 alloy in aluminum die-casting. In-situ synthesized titanium matrix composites and H13 tool steel were immersed in molten A380 alloy in a mold at 993 K for times varying from 0 to 1200 s. In-situ synthesis TMCs and interfacial reaction between TMCs and A380 alloy were examined by X-ray diffraction, optical microscope, scanning electron microscope and electron probe micro-analyzer. The reaction behavior shows that TMCs can a substitution for H13 tool steel.

Abstract: The aim of this study is to evaluated the possibility of the in-situ synthesized (TiC+TiB) reinforced titanium matrix composites (TMCs) for the application of structural materials. In-situ synthesis and casting of TMCs were carried out in a vacuum induction melting furnace with Ti and B4C. The synthesized TMCs were characterized using scanning electron microscopy, an electron probe micro-analyzer and transmission electron microscopy, and evaluated through thermodynamic calculations. The spherical TiC plus needle-like and large, many-angled facet TiB reinforced TMCs can be synthesized with Ti and B4C by a melting route.

Abstract: The aim of this study is to clarify the alpha-case formation mechanisms for the economic net-shape forming of Ti and Ti alloys. The α-case formation reaction between Ti and Al2O3 mold was examined in a plasma arc melting furnace. The reaction products were characterized by using an electron probe micro-analyzer and transmission electron microscopy. The α-case generation between Ti and Al2O3 mold could not be explained by the conventional α-case formation mechanism, which is known to be formed by the interstitials, especially oxygen dissolved from mold materials. However, on the basis of our experimental results and thermodynamic consideration, it was confirmed that the α-case is formed not only by interstitial oxygen atoms but also by substitutional metal atoms dissolved from mold materials. Based on the α-case formation mechanism, α-case free net-shape forming of Ti and Ti alloys could be possible for biomedical applications.

Abstract: The aim of this study is to investigate the applicability of titanium matrix composites (TMCs) sleeve to Al alloys die-casting. Ti and 1.88 mass% B4C were prepared for the synthesis of 10 vol% (TiC+TiB) hybrid TMCs. In-situ synthesis and net-shape forming of TMCs were carried out in a vacuum induction melting furnace. The synthesized (TiC+TiB) TMCs were examined using scanning electron microscopy, an electron probe micro-analyzer, X-ray diffraction and transmission electron microscopy. The resistance-ability of (TiC+TiB) TMCs to molten Al alloys attack was also examined. Their reactions were carried out in a furnace at 993 K for times varying from 0 to 1200 s. In the case of conventional sleeve material, H13 steel, there were severe interfacial reactions and erosion after 60 s. On the other hand, the resistance of (TiC+TiB) TMCs to interfacial reactions and erosion by molten A380 alloy was significantly increased.

Abstract: Alpha-case formations between investment molds and TiAl alloys were investigated for economic TiAl alloys net-shape forming. The α-case reactions between mold and TiAl alloys were characterized by using optical microscopy and a hardness tester. In the case of TiAl alloys, there were no α-case formation reactions. The α-case was formed not only by interstitial oxygen elements but also by substitutional metallic elements dissolved from mold materials. There were neither interstitial nor substitutional α-case formations since TiAl alloys have both negligible solubility of oxygen and low activity in molten states. The results of the investment casting of TiAl alloys confirmed that the casting route in our study can be an effective approach for the economic net-shape forming of TiAl alloys automotive parts.