Papers by Author: Tian Liang Zheng

Abstract: Four fluorinated polyacrylate dispersions, which based on chlorotrifluoroethylene (CTFE), acrylic acid (AA), vinyl acetate (VAc) and ethenyltriethoxysilane (ETOS) as monomers, are synthesized by free radical polymerization. The influence of xenon lamp and UV-light aging on the film with the fluorine content is discussed. The effect of salt-spray corrosion before and after UV-light aging with F wt% of film is also studied. The results show that low surface energy of high fluorine content film can retard salt-spray corrosion compared with no or low fluorine content films.

Abstract: A novel environmental protective water based metallic coating was developed for aluminum alloys, which mainly contains metal flake, silicate and silane. The coating's properties were investigated by neutral salt spray test, micro-hardness testing, adhesion test and electrochemical technique etc. Meanwhile the coating's surface and microstructure was observed by scanning electron microscopy (SEM). Furthermore, the film forming matter was examined by Fourier transform infrared spectroscopy (FTIR) test. Results showed that an excellent adhesive, heat-resisting, protective coating for aluminum alloy could be achieved by this technique. An interpenetrating polymer network (IPN) was formed in the coating by means of cross linking reaction of organosilicone and inorganic silicate. In thesis, the film forming mechanism and protection of coating were also discussed.

Abstract: Magnesium and its alloys have many applications for theirs excellent physical and mechanical properties. Due to magnesium’s active chemical properties and difficulties in direct painting, a novel environmental protective water based coating was developed, which mainly contains metal flake, silicate, silane and sodium polyphosphate etc. The properties and structure of the coating were investigated by adhesion test, hardness test, heat resistance test, neutral salt spray test and Scanning Electron Microscopy (SEM) et al. Meanwhile, the effect of sodium polyphosphate was also examined by hydrogen evolution test and electrochemical test. Furthermore, the film forming mechanism of the coating was explored by Fourier Transform Infrared spectroscopy (FTIR). Results showed that the coating had a stepped structure which could achieve extraordinary adhesion, 350°C temperature heat resistance, HV0.50/30 210 hardness and 300 hours anti-corrosion time in salt spray test. In the coating, the addition of sodium polyphosphate could greatly improve the corrosion resistance of the coating because of the barrier film formed by sodium polyphosphate. The mechanism of interpenetrating polymer network (IPN) was preliminary put forward based on the results of FTIR.

Abstract: Influence of SO2 concentration on initial corrosion of aluminum was studied in simulated marine atmosphere. Variation of initial corrosion morphology, relation between weight gain and time in the course of initial corrosion, corrosion speed (token with maximum pitting depth and weight gain) were analyzed and discussed. Primary results is list below: In marine atmosphere, SO2 sedimentation above 0.1 mg/100cm2 can accelerate Al pitting with low Cl- sedimentation. Both corrosion weight gain and pitting depth increase obviously. For pitting surface of LY12 with SO2 and Cl- sedimentation, corrosion potential change little, Nyquist Graph was single arc of capacitance resist with retractile real part, Rr can’t reflect corrosion degree.