Papers by Author: Tohru Yamasaki

Abstract: Ti-Nb alloys in deionized water and Hanks' balanced salt solution were investigated at 310K using a ball-on-disc type frictional test machine with a ZrO2 ball counterface. In this study, besides the fretting wear behavior of Ti-Nb alloys was investigated, the relationship between the microstructure and mechanical properties of the Nb-added Ti alloy was investigated, and the relationship between the composition and hardness on the fretting wear of the alloy will be clarified from the results of the wear volume and surface analysis of wear track. The results obtained from the frictional test indicate that the dynamic coefficient of friction converged to a constant value with time variation. Also, wear volume in HBSS was smaller than in water, and wear volume of heat-treated became smaller than As-Rolled. Microstructural observations suggest the scars of adhesive wear were observed. Comparing each morphology, the ratio of the peeling part was more significant in Ti-Nb alloys, which have α+β than in Ti-Nb alloys, which have only β. Moreover, the results of Open circuit potentiometry indicate that the corrosion potential difference increased with wear. This is most likely due to the passive film was damaged. Besides, the corrosion potential difference of β-Ti-Nb alloy heat-treated with HBSS is small. It is assumed that there is an influence of HBSS besides the fine structure.

Abstract: One of the applications of titanium in the dental field is a porcelain-fired-metal crown. It is made by firing porcelain multiple times with different composition of ceramics on a metallic abutment tooth. Regarding firing process to metallic abutment, a primer is generally required to be applied in advance of a porcelain firing and the opaque porcelain is applied to cover the metallic color of the abutment. By the way, our recent research shows that white oxide films formed on the Ti substrate have a color tone similar to opaque porcelain. Therefore, porcelain-fired-Ti samples replacing primer and opaque porcelain firing with the TiO2 oxide layer were fabricated and evaluated in this study. Color tone and peel strength were evaluated, and cross-sectional observation was observed by SEM and EPMA.

Abstract: Synthesis of Sr₃Zn₂Fe₂₄O₄₁ Z-type ferrite was investigated. Precursors of ferrite were prepared by polymerizable complex method. Identification of formed phases in the obtained samples and determination of lattice parameters of Z-type ferrite were performed by powder X-ray diffraction (XRD). Single-phase of Sr₃Zn₂Fe₂₄O₄₁ Z-type ferrite was synthesized by heating at 1463 K for 5hours in air. M-H curve of prepared single-phase Sr₃Zn₂Fe₂₄O₄₁ Z-type ferrite was measured by using vibrating sample magnetometer (VSM). It was revealed that Sr₃Zn₂Fe₂₄O₄₁ Z-type ferrite has larger saturation magnetization (23.5 μ_B/formula unit) than that of Sr₃Co₂Fe₂₄O₄₁ (22.7 μ_B/formula unit) and shows characteristic two-step saturation of magnetization as well as Sr₃Co₂Fe₂₄O₄₁ Z-type ferrite.

Abstract: Synthesis of U-type hexaferrite was investigated in the various strontium-based systems (Sr-Me-Fe-O system, Me = Co, Zn, Cu, and Ni). Precursors of ferrites were prepared by polymerizable complex method. Sr₄Me₂Fe₃₆O₆₀ (Me = Co and Zn) U-type hexaferrites were synthesized at the temperature range between 1423 and 1483 K in air. Coercivity of obtained ferrite was decreased with increasing heat treatment temperatures. Cu substitution reduced formation temperature of U-type hexaferrite.

Abstract: The tensile specimen of nanocrystalline Ni–W alloys with 50 μm × 20 μm in area and 4 mm in gauge length was made by using an electrodeposit together with ultraviolet light lithographic technique. The composition and grain size were Ni-16.9 at.% W and about 6 nm, respectively. Tensile testing of the alloy was carried out. The nominal tensile strength and Young’s modulus were about 2.7 GPa and 123 GPa, respectively. The elastic strain and plastic strain were about 2 % and 1 %, respectively. The stress-strain curve showed work hardening. The macroscopic fracture part yielded necking and the microscopic fracture surface showed dimple pattern. As mentioned above, this electrodeposited nanocrystalline Ni-W alloy showed high strength, low elastic modulus and high ductility.

Abstract: Some amorphous Fe-Cr-P-C coating films having high hardness and high corrosion resistance have been produced by a newly developed thermal spraying technique. In order to control the temperatures of the powder particles in the flame spray and the substrate, a newly developed cylindrical nozzle, with external cooling nitrogen gas, was mounted to the front end of the thermal spray gun. Fe70Cr10P13C7 films with various external cooling gas velocities between 20 m/s and 40 m/s exhibited entire amorphous structure without oxides and/or unmelted particles. Corrosion-resistance of the films was observed in immersion tests using various corrosive liquids.

Abstract: Viscous flow behaviour of supercooled liquids and mechanical properties in Zr55+XCu30-XNi5Al10 (X=0, 5 and 10 at. %) and Zr65Cu18Ni7Al10 bulk metallic glasses (BMGs) have been examined. Viscosity has been measured by using a penetration viscometer at a high-speed heating rate of 400 K/min. With increasing Zr-content, Tg tended to decrease and Tx tended to increase, resulting Tx (=Tx-Tg) increaseing up to about 170 K under a heating rate of 400 K/min by the DSC analysis. The viscosity lowered about one order of magnitude, e.g., minimum value of the viscosity decreased from 3~4x106 Pa-s for the Zr55Cu30Ni5Al10 and Zr60Cu25Ni5Al10 BMGs down to 5~6x105 Pa-s for the Zr65Cu20Ni5Al10 and Zr65Cu18Ni7Al10 BMGs under the same heating condition. Compression tests were also carried out at a slow strain rate of about 1 x 10-4 s-1 at room temperature. With increasing Zr-content, the apparent yield stress was decreased but the total strain at fracture was increased significantly, suggesting that there is a strong relationship between viscosity and the mechanical properties in these BMGs.

Abstract: In order to examine the correlation between a mechanical property and an excess free volume for metallic glass Pd44Cu31Ni8P17, longitudinal and transverse ultrasonic velocities were measured to estimate longitudinal and transverse elastic constants, c11 and c44. An as-quenched sample, an annealed one at a temperature just below a glass transition temperature Tg and a crystalline one were prepared. The as-quenched sample contains the excess free volume depending on the preparing process. The Young’s modulus E, the Poisson’s ratio, a bulk modulus and c12 are estimated using c11 and c44. The values of c11, c 44 , c12 and E of the as-quenched one are smaller than those of the annealed sample losing excess free volume by about 0.2 % and much smaller than those of the crystalline one. The Poisson’s ratio for the as-quenched sample and the annealed one are 0.389 and 0.387, respectively, which are much larger than that for the crystalline one with 0.349.

Abstract: High-strength nanocrystalline Ni-W alloys containing 16.9 at. % W with average grain size of about 6 nm in diameter has been obtained by electrodeposition. At room temperature, the nominal tensile strength of the alloy was attained to about 1600 MPa, while the plastic strain before fracture was a very low value of 0.05 %. In this case, highly localized shear bands were observed near the fractured surface of the tensile test specimen. When the samples were annealed at 300 °C under a static tensile stress of 327 MPa, the plastic strain was largely increased at the initial period of annealing and then tended to saturate, i.e., 0.54 % for 2 h, respectively. Grain size of the Ni-W alloys was almost saturated to 10 ~ 15 nm after annealing at 300°C for 2 h. It may be expected that the high tensile stress during grain growth might be effective to obtain the large uniform plastic deformation of nanocrystalline Ni-W alloys.

Abstract: Viscous flow behavior in supercooled liquid region of as-cast and pre-annealed Zr55Cu30Al10Ni5 bulk metallic glasses has been examined by using a penetration viscometer under high-speed heating rate of 20, 200 and 400 °C/min. Applied load for the cylindrical-shaped penetration indenter with a diameter of 1 mm was varied from 0.049 N to 0.294 N. Viscosity was quite independent of these applied loads. By pre-annealing the bulk metallic glasses at 400 °C, the density of the glasses increased, while the viscosity and the activation energy for viscous flow in their soopercooled liquid decreased with the pre-annealing treatments. Corresponding measurements of the differential thermal calorimetry (DSC) have been also done.