Papers by Author: Tuomas van der Meer

Abstract: The effect of different microbial consortia on the leaching of chalcopyrite was studied at different temperatures and solution compositions with Boliden’s Aitik ore in column reactors simulating heap bioleaching. The columns were equipped with sampling chambers and chalcopyrite mineral electrodes in order to investigate the passivation of chalcopyrite. The sampling chambers were filled with agglomerated ore and pieces of chalcopyrite-rich ore. In addition to chemical analysis of the leaching solution and solids the progress of leaching of chalcopyrite was studied by continuous potential measurements with chalcopyrite electrodes. The occurrence and composition of potentially passivating layers on the surfaces of the electrodes and the samples taken from sample chambers were examined by optical and scanning electron microscopy.

Abstract: An overview is presented of a multi-year research effort on developing high-rate fluidized-bed bioprocesses for ferric sulfate production to be used as a unit process in various hydrometallurgical applications including indirect tank leaching of ore concentrates, regeneration of heap leach liquors and control of iron containing acidic mine wastewater. Iron oxidation rates of over 26 kg m-3 h-1 were achieved at hydraulic retention times of less than 1 h at 37 °C. Oxygen supply became the rate-limiting factor even with 99.5% dioxygen aeration. Fe2+ oxidation proceeded at pH below 1 even in the presence of 60 g Fe3+ L-1 allowing the regeneration of concentrated ferric sulphate solutions required in indirect tank leaching of sulfidic ore concentrate applications. Of several tested FBR carrier materials activated carbon was the most suitable based on its availability, long-term durability and the achieved high iron oxidation rates. Jarosite precipitates accumulating to the top of the inert carrier materials played an important role in the FBR biomass retainment. For regeneration of synthetic and actual sulfidic ore heap leaching liquors, a gravity settler was installed in the recycle line of the FBR. The system produced iron precipitates with good settling characteristics and settling tank effluent with low turbidity and suspended solids concentrations. These results revealed the potential of FBR process in both heap leach liquor regeneration and controlling the iron containing waste streams. The PCR-DGGE-partial seguencing of the 16S rRNA gene protocol revealed that the FBR culture at 25-37 °C remained dominated by Leptospirillum ferriphilum over a range of operational conditions studied over the years. A modeling approach for managing Fe3+ production by FBR in combination with heap leaching was based on an artificial neural network-back propagation algorithm (ANN-HEAP) and resulted in excellent match between the measured and the predicted concentrations. High-rate fluidized-bed iron oxidation is amenable to regeneration of tank and heap leaching solutions as well as controlling iron containing waste streams.