Papers by Author: Vera G. Sursaeva

Abstract: The migration of individual special [ ] 0 1 10 tilt grain boundary (GB) with Σ =15 and misorientation angle 29° in Zn bicrystal have been investigated. The stationary shape of migrating GB has been studied and the migration rate has been measured by optical microscopy in situ between 558 and 683 K using polarized light. In certain experimental runs the migrating GB is faceted and moves thermally activated. Its kinetics follows the Arrhenius type dependence despite the fact that shape of moving GB depends on temperature. After detachment from impurity cloud the [ ] 0 1 10 tilt GB migrates activationless in the temperature interval 618÷683 K. The detachment temperature is 618 K. The non-physically high value of the apparent migration activation enthalpy can appear due to the change of GB shape from faceted to smooth and back.

Abstract: Texture formation during secondary recrystallization depends on the nature of secondary recrystallization process itself. So microstructure evolution and texture development during secondary recrystallization should be discussed concurrently. The main goal of the paper is studying of the effect of internal stresses on grain boundary motion or, more generally, the interaction of grain boundaries with stress fields and the effect of deformation inhomogeniety on grain boundary mobility during secondary recrystallization. Considering transformation from normal grain growth to secondary recrystallization, the attempt was made to characterize the microstructure and to relate it to the processes of nucleation and growth of new rains. The nucleation process is heterogeneous. The data allow us to assume that the nuclei are strain free grains.

Abstract: Reflected light optical analysis and Electron Backscatter Diffraction (EBSD) analysis have been used to m easure grain sizes in 2D Al foil samples, annealed for different times. There are significant differences in the results of the two techniques. It is shown that in Al it is possible to detect boundaries in optical images down to a misorientation angle of 7-8º. Nevertheless, in most samples the critical angle of easy etching lies above 10º. The observed differences in grain size measurements between optical analysis and EBSD analysis can be largely attributed to three phenomena: (1) individual samples may behave slighty differently due to differences in the effectiveness of etching (2) the grain size is heterogeneous over large areas and (3) the effect of etching is not only a function of misorientation angle but also grain boundary plane. Despite these uncertainties, optical analysis seems to be reliable for analysis of processes in which mainly grain boundaries with misorientation angle of > 10º are involved i.e. grain growth.

Abstract: The experimental results on motion of single grain boundaries (GBs) of natural mechanical twin and single fabricated twin GBs as well as on fabricated twin GBs in system with triple junction (TJ) are obtained. The mobility of natural mechanical twin GBs, fabricated single GBs and fabricated GBs with TJ are compared. For the first time the effect of detachment of moving TJ and single natural twin GB from adsorbed atoms is reported. The results on single GB migration are considered in context of triple junction migration as the step to grain growth, i.e. “polycrystal” experiments.

Abstract: First results from grain growth experiments in a columnar structured Al foil show several interesting features: (a) the grain size distribution remains heterogeneous even after up to 300 min. annealing and (b) the Von Neumann-Mullins relation is not always satisfied. To clarify the underlying reasons for these features, in-situ heating experiments within a Scanning Electron Microscope (SEM) were combined with detailed Electron Backscatter Diffraction (EBSD) analysis. These show that the movement of boundaries can be strongly heterogeneous. For example, the complete replacement of one grain by a neighbouring grain without significant change of the surrounding grain boundary topology is frequently seen. Experiments show that grain boundary energy and/or mobility are anisotropic both with respect to misorientation and orientation of grain boundary plane. Low energy and/or mobility boundaries are commonly low angle boundaries, twin boundaries and boundaries that form traces to a low index plane of at least one of the adjacent grains. As a consequence the Von Neumann-Mullins relation is not always satisfied.

Abstract: When a bicrystal or polycrystal are subjected to a change in temperature, the individual responses of the two adjoining crystals may differ in a manner, which tends to produce a dilatational mismatch along grain boundaries. If compatibility is to be retained along the interface, an additional set of stresses must then be generated in order to conserve this compatibility. ‘Compatibility stresses’ will also be generated whenever a polycrystal is heated or cooled and the thermal expansion coefficients of the individual grains are different due to thermal expansion anisotropy. In such cases adjacent grains will attempt to change dimensions and develop mismatches by amounts controlled by the parameter Δa*ΔΤ, where Δa is the difference between the thermal expansion coefficients in the appropriate directions, and ΔΤ is the temperature change. These ‘compatibility stresses’ may be relieves if grain boundary motion, triple junction migration and grain growth are possible. These ‘compatibility stresses’ may play important role in the kinetic behavior of the microstructure ranging from influencing the behavior of lattice dislocations near the grain boundaries to promoting grain boundary and triple junction dragging or moving. The motion of the ‘special’ grain boundaries, triple junctions with ‘special’ grain boundaries and twins under the influence of internal mechanical stresses is the main subject of this paper.

Abstract: The migration of the systems of tilt grain boundaries with a triple junction (<100>, <110> and <111>) in high-purity aluminium are presented. The experimental results demonstrate that the motion of grain boundary systems with triple junctions in Al at low temperature can be controlled by slowly moving triple junctions. In the high temperature range the triple junctions less affected the motion of the systems and the activation enthalpy was smaller than that at low temperature. The experiments revealed a drastic difference between activation enthalpy of grain boundary and triple junction motion at different temperatures. The compensation effect (linear dependence of migration activation enthalpy on preexponential mobility factor) at the migration of the systems with triple junction was observed. The compensation temperature was revealed to be close to the temperature for the triple junction mobility.