Papers by Author: Xu Hui Mao

Abstract: In China’s freshwater environment, the eutrophication phenomenon has become more and more serious in recent years. The changes of water quality may induce the variation of metal’s corrosion behavior. In this paper, carbon steel as common material of hydraulic structure was the investigated object, and its early corrosion behavior affected by microbes (algae and microbe) in eutrophic lakes was studied using immersion test, electrochemical measurements and infra-red spectrometry techniques. The experimental waters were natural eutrophic water and microbescleaned water. The former was fetched from eutrophic East Lake in Wuhan City, Hubei Province of China, and the preparation of later was making natural eutrophic water sterilized and algae removed by UV radiation. In order to present the changes of carbon steel’s corrosion behavior in natural eutrophic freshwater with and without microbes, comparative experiments were conducted in lab. Both weight loss method and electrochemical techniques showed that, the corrosion rates of carbon steel decreased in early stage for the influence of microbe existence. The analysis of infrared spectra indicated that, corrosion product on the surface of coupons taken from natural eutrophic water, mainly were δ hydroxyl ferric oxide, magnetic iron ore, γ hydroxyl ferric oxide, α hydroxyl ferric oxide and β hydroxyl ferric oxide, with relative concentration ratio of 1:0.314:1.003:0.634: 0.654. While corrosion product on the surface of carbon steel taken from the microbes-cleaned water, mainly were α hydroxyl ferric oxide and γ hydroxyl ferric oxide, with relative concentration ratio of 1:1.215.

Abstract: With suitable pretreatment, a compact and even nickel-phosphorus alloy coating was obtained on W-Cu alloy by electroless deposition from solutions containing nickel sulphate as a source of nickel and sodium hypophosphite as the reducing agent and a source of phosphorus. The Ni-P coating was normally prepared from acidic baths at high temperature of the order of 90oC with the pH of 4.8 and it was smooth and uniform and exhibited high crystal refinement and high microhardness and superior corrosion resistance. The microhardness, adhesion and corrosion resistance mechanism of Ni-P deposit were studied. The microhardness of the Ni-P alloy deposit increases greatly by tempering at various temperatures. The Ni-P deposit has a strong adhesive force with W-Cu alloy substrate checked by thermal shock test and scribe test. The anti-corrosion ability of Ni-P coating and its anti-corrosion mechanism were measured using immersion experiment and potentiodynamic polarization techniques. The results showed that the corrosion resistance of Ni-P coating was higher than that of W-Cu alloy substrate in the 10vol.% sulfuric acid, monitoring sweat solution and 3.5wt.% sodium chloride solution. The anti-corrosion mechanism of electroless Ni-P coating immersed in 3.5wt.% sodium chloride solution was studied using potentiodynamic polarization techniques. The surface micromorphological morphology and structure of the Ni-P coating were investigated using Scanning Electronic Microscope (SEM) and X-ray Diffraction (XRD). The results indicated that the Ni-P alloy coating consisted of microcrystals and it was amorphous in structure, and the electrochemical measurement showed passive film formed on Ni-P coating during immersion test in the 3.5wt.% sodium chloride solution.