Papers by Author: Yasin Genc

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Abstract: In this study, hydroxyapatite (HA) material, obtained from calcinated bovine bone (BHA), was mixed with 0.25, 0.50, 1.00, and 2.00 wt% Li2CO3. The pressed pellets were sintered at various sintering temperatures between 900°C and 1300°C. Measurements of compression strength, microhardness, and density, along with SEM observation and X-ray diffraction analysis were performed. The experimental results showed that the samples with 0.25 and 0.50% Li2CO3 reached a maximum of densification and the highest values of compression strength and microhardness were achieved after sintering at 1300°C. The wetting effect of a Li2O-associated glassy phase was observed even from 900°C.
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Abstract: Bovine derived hydroxyapatite was doped with partially stabilized zirconia with 3 mol% yttria. The influence of sintering temperature and the amount of the incorporated zirconia on densification, mechanical properties, crystalline structure and microstructure was investigated. The results indicate that the produced materials exhibit poorer mechanical properties than the relevant composite materials of enamel derived hydroxyapatite. This difference can be attributed to F, since F-content in bone is much higher than in enamel. Hence, in the light of the prospective use of the investigated materials in biomedicine, bovine derived hydroxyapatite doped with zirconia can potentially serve as graft material for load bearing applications if very small amount of F can be incorporated, in order to resemble the composition of enamel derived apatite.
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