Authors: Jin Zhang, Nan Guo Jin, Ye Tian, Xian Yu Jin
Abstract: As a porous medium, the strength of cement-based materials is significantly affected by its porosity. This paper presents a new method to describe the strength development of cement-based materials as a function of porosity based on a developed microstructure hydration model of cement. The hydration model deduces the relationship between the diameter change of cement particle and time based on Krstulović-Dabić hydration kinetics formulas and extends a broader version by considering the effect of water reduction, temperature variation, interfacial contact area between hydration products and free water on the hydration rate. Using the hydration model, the time-varying development of porosity can be obtained. Then, based on the strength model proposed by Maekawa et al, in which both the present and initial porosity are taken into account, a new method was established to predict the strength evolution with the porosity calculated by the hydration model.
502
Authors: Xin Li, Nan Guo Jin, Ye Tian, Xian Yu Jin
Abstract: Capillary absorption effect is very important to the research of concrete durability. Initial surface absorption test (ISAT) method has been employed to investigate the effect of W/C, age, aggregate volume percent and concentration of NaCl solution as a transmission medium of the capillary absorption of the cement-based materials. Experiment results indicate that, the capillary absorption coefficient increases with the increasing of W/C, but decreases with the increasing of age and aggregate volume percent. Within a certain range of low concentration, the capillary absorption coefficient increases with the increasing of the concentration of NaCl solution, however when the concentration is too high, the transmission rate will be lower than pure water. This investigation provides an experimental foundation for the durability design and service life assessment of concrete structures.
2644
Authors: Jin Yang Sun, Nan Guo Jin, Ye Tian, Xian Yu Jin
Abstract: In this research, an experiment was designed to study the capillary absorption of fly ash concretes. In order to understand the essence of capillary absorption, samples of fly ash concrete with different heights at different curing ages were tested in this experiment. It is found that the samples tested at 7d and 28d had the same sorptivity. And the height of the samples has no influence on the capillary absorption.
78
Authors: Jun Chen, Xian Yu Jin, Ye Tian, Nan Guo Jin
Abstract: In this work, the correlation of mechanical and microstructure development of early-age concrete was studied through electrical resistivity measurement. The inner enhancement of hydration products other than evolution of pore structure was identified as a vital factor for microstructural development of early-age concrete, which embodies in the increase of tortuosity a and significantly contributes to the growth of mechanical properties. Finally, a correlation between compressive strength and two crucial microstructural parameters (effective porosity ϕeff and tortuosity a) was built for the three mixes of concrete studied in this paper.
1818
Authors: Ye Tian, Zongjin Li, Hong Yan Ma, Xian Yu Jin, Nan Guo Jin
Abstract: In this research, the physical and chemical influence of polyacrylate (PA) latex on cement-based materials were studied using polymer modified mortars with polymer/cement (P/C) ratios of 0%, 5% and 10%. Physically, the mechanical performance of PA latex modified mortars was investigated with compression toughness energy and bending strength. Further more, a comparison of the pore structure and porosity between PA latex modified and unmodified mortars was conducted. The chemical reactions between PA polymer and cement hydrates were clarified with thermogravimetric (TG) analysis. It can be concluded from this research that PA polymer can refine the pore structure of cement mortars and link the cement hydration products together chemically. While, at the same time, PA latex addition can cause air entrainment which will weaken the physical behavior of cement mortars. So there is an optimum P/C ratio to achieve the best mechanical properties. And in this research, the optimum P/C ratio is 5%.
807
Authors: Ye Tian, Xian Yu Jin, Yuan Zhan, Nan Guo Jin
Abstract: This paper reports the investigation on both high and normal strength concrete using a non-contact electrical resistivity facility. The bulk resistivity development (ρ(t)-t curves) of the fresh concretes was evaluated from casting to 72h. The relationship between the electrical resistivity and the pore structure obtained from mercury intrusion porosimetry (MIP) method was analyzed. And the compressive strength evolution of fresh high- and normal- strength concrete was studied based on the bulk resistivity at early ages. The experiment results indicated a linear relationship between the fractional porosity and electrical resistivity. A further correlation between the compressive strength and electrical resistivity was analyzed with Archie’s law. Based on these studies, it appears that the electrical resistivity test could provide information for the design, quality control, quality assurance, and utilization of both high- and normal- strength concrete.
122
Authors: Chuan Qing Fu, Xian Yu Jin, Ye Tian, Nan Guo Jin
Abstract: Based on the MFPA2D software system and test method of the wedge splitting fracture in the Lab., a numerical model was established. The numerical experiments on wedge splitting fracture with plain concrete and SFRC (steel fiber reinforced concrete) were carried on. The calculation results about plain concrete with different dimensions and ligament length proved the numerical model is effectively on numerical calculation, and have a good agreement with the results of the test results. Then, the process of crack initiation, propagation of SFRC specimens with different dimensions and fitting formula about size effect were given. The results indicated that the size effect existed in the splitting fracture energy of SFRC.
335
Authors: Hui Zhen Jin, Qiang Li, Xian Yu Jin, Ye Tian, Nan Guo Jin
Abstract: Boric acid (H3BO3) is often used for cooling the heat in nuclear power plant. Though the drastic measures have been taken, the potential leakage still can not be fully eliminated. Therefore, an attempt to understand the durability mechanism of RC subjected to boric acid is of vital importance. In this paper, specimens cured in a standard moist room at a temperature of 20 ±3 °C after 28days were immersed in three different concentration of boric solution (2000ppm, 8000ppm, 30000ppm) artificially simulated to accelerate the corrosion of acid environment. The hydration products are investigated. Microstructure of reinforced concrete on the surface, 2cm and 4cm away from the surface at ages of 60, 90 and 150 days are examined using X-ray diffraction (XRD) and scanning electron microscope (SEM) respectively. Results indicate that main hydration product is Ca(BO2)2,boric acid corrosion to concrete surface can only be detected from the specimens in 30000ppm solutions at the ages of 150 days and its effect is slight. However, the inner part of the concrete was not affected. The results of XRD coincide with those of SEM.
252
Authors: De Jin Xu, Chuan Qing Fu, Xian Yu Jin, Ye Tian, Nan Guo Jin
Abstract: Cement concrete has an increasing utilization in highway construction. However, the lower flexural tensile strength and abrasion-resistance restricted the development of concrete pavement with heavy traffic. Hence, It has highlighted the need for research on high performance concrete (HPC). The design of specific concrete normally depends on the mixing of mineral admixtures in concrete mixture. This paper presents the first experimental study on strength and abrasion-resistance enhancement admixture (SAEA) mixed with slag powder, steel slag powder and silica fume. The optimal proportion of three mineral admixture and reasonable mixed amount of SAEA were then given, and the mechanism of SAEA reacted in concrete was analyzed based on sol-gel theory. Lastly, the effect of concrete mixed with SAEA was validated and the micro-structure transformation of specimens was given by SEM.
247
Authors: Yuan Zhan, Qiang Li, Xian Yu Jin, Ye Tian, Nan Guo Jin
Abstract: Reaches on durability of concrete has been made great advances over the past decades. However, little works have been done on the corrosion of reinforced concrete exposed to boric acid in cooling pond of heating exchange system of nuclear power plant. The purpose of this study is to experimentally investigate the behavior of reinforced concrete in such circumstance. Tests were carried out on specimens cured in a standard moisture room at a temperature of 20±3°C. Three different concentration of boric solution (2000ppm, 8000ppm, 30000ppm) were simulated to accelerate the corrosion. The compressive and splitting tensile strength,elastic modulus of concrete , mass loss rate of steel bar, bond strength and flexural bearing capacity of reinforced concrete at 60, 90, 120, 150 and 180 days were obtained respectively. The results indicate that the presence of boric acid below 30000ppm does not significantly affect serviceability of concrete. The corrosion is slight for the specimens with crack less than 0.4 mm under flexural loads. Boric acid almost has no effect on the corrosion of the steel bar and bond strength.
242