Papers by Author: Yoon Bok Lee

Abstract: Cadmium selenide(CdSe) nanoparticles were prepared in the aqueous solution containing isopropyl alcohol by the ultrasonic irradiation at room temperature. The cadmium chloride (CdCl2) and sodium selenosulfate (Na2SeSO3) were used as the cadmium and selenium source, respectively. X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), transmission electron microscopy (TEM), UV-Vis absorption spectra and PL spectra were used to characterize the CdSe nanoparticles. XRD analysis revealed the formation of cubic structure CdSe. TEM images showed aggregated CdSe nanoparticles with the size of nanometer scale. Average size of CdSe nanoparticles were about 3.9, 5.0 and 5.1nm with sonication time of 6, 30 and 40 minutes, respectively. The surface emission became less intensive and shifted to red with increasing irradiation time. This paper presents the effects of ultrasonic on the formation of CdSe nanoparticles and its characteristics.

Abstract: Cadmium selenide (CdSe) of hollow sphere with 30-50nm in diameter have been prepared form the mixed solution of cadmium chloride (CdCl2), sodium selenosulfate(Na2SeSO3) and ethylenediamine (H2NCH2CH2NH2) at room temperature. The hollow sphere of CdSe was characterized by transmission electron microscopy (TEM), high resolution transmission electron microscopy (HRTEM) and X-ray diffraction (XRD). The molar ratio of EDA to Cd2+ ions in this system was important factor on controlled synthesis in the self-encapsulated morphology. Based on the observation on morphological difference with molar ratio of EDA to Cd2+ ion, the possible mechanism for the formation of CdSe hollow sphere was discussed.

Abstract: CdSe nanoparticles with average particles size of ~ 3.4 nm were successfully prepared by the sonochemical reduction of a mixed solution of CdCl2, Na2SeSO3 and CH2CH2OH)2NH at room temperature. CdSe nanoparticles characterized by TEM, XPS and XRD analysis revealed the formation of high purity cubic phase CdSe nanoparticles with lattice constant of a=6.415Å. CdSe nanoparticles showed relatively large range of particle size distribution from 20 to 50 nm as the sonication time increased. UV-Vis absorption spectra showed a red-shift in the wavelength region of 545-590 nm as increasing sonication time due to the gradual growth of CdSe nanoparticles in the solution. This paper will mainly present the effects of ultrasonic irradiation on the formation and properties of CdSe nanoparticles.

Abstract: Cadmium selenide (CdSe) have been prepared by the reduction of mixed solution of cadmium chloride (CdCl2), sodium selenosulfate (Na2SeSO3) and diethanolamine ((CH2CH2OH)2NH) at temperatures of 80-200°C under Ar atmosphere. Characteristics of CdSe nanoparticles were analyzed using transmission electron microscopy (TEM), x-ray photoelectron spectroscopy (XPS) and x-ray diffraction (XRD) and UV-Vis absorption spectra. CdSe samples prepared at relatively low temperature of below 100°C showed cubic structure while samples synthesized at temperature above 100°C showed hexagonal phase. The increased reaction temperature caused the particle size increase as well as the agglomeration of particles to form a hollow sphere. UV-Vis absorption spectra also showed a red-shift as increasing reaction temperatures due to the gradual growth of CdSe nanoparticles in the solution. The relatively sharp absorption band from samples synthesized at 80 and 100°C can be attributed to homogeneous particle size distribution compared with those of prepared at elevated temperatures. This paper will mainly discuss the phase stability of CdSe nanoparticles as well as the hollow sphere formation.

Abstract: Nickel powders were synthesized by the reduction of hydrazine of nickel salts from diethanolamine (DEA) solution, and the morphological characteristics of nickel powders were investigated with various process conditions such as the addition of hydrazine, reaction temperature, the composition of mixed solvents. The addition of hydrazine in DEA solution largely affected the size control of nickel powders. Under N2H4/Ni2+molar ratio= 1.5 and 2.0 conditions, spherical nickel powders in the submicron range were obtained owing to higher the reduction rate. An increase of temperature increased the size of nickel particles. At 220°C for 40min, the nickel powders were composed of polyhedral particles with a high crystalline in the submicron range. The mixed volume ratio of TEA to DEA solvent improved the inhibition of agglomerate between particles.

Abstract: Nickel powders were prepared by the reduction of hydrazine of Ni(OH)2 reactant slurries from non-aqueous media. The morphological characteristics of nickel powders were investigated under various processing conditions. Nickel powders were characterized by using scanning electron microscope (SEM), X-ray diffractometer (XRD), thermal gravitational analysis (TGA) and X-ray photoelectron spectroscopy (XPS). The size of nickel powders was increased as the reaction temperature and time increased because of the thermal agglomeration of nuclei and/or increased growth rate. The surface of nickel powders composed of both Ni and Ni(OH)2 was oxidized in the temperature range of 400-600°C.