Authors: Yao Ning Sun, Ding Fan, Yu Feng Zheng, Min Zheng, Jian Bin Zhang
Abstract: Laser cladding technique was used to form Ni3Si intermetallic composite coating reinforced by
in-situ formation NbC particles on Ni-based superalloy substrate. The process parameters were optimized
to obtain cladding. The effect of Nb-C addition to the microstructure of the coating was investigated. The
morphology of reinforcement particles was discussed. The experimental results showed that an excellent
bonding between the coating and the substrate was ensured by a strong metallurgical interface. The clad
coating was very good and free from cracks and pores. The microstructure of the coating was mainly
composed of Ni(Si), Ni3(Si, Nb) and NbC. The NbC particles were formed by in-situ reaction between Nb
and C during laser cladding process. NbC particles were homogeneously distributed in the composite
material. Moreover, the maximum size of NbC particles was more than 4 μm.
1351
Authors: Yu Feng Zheng, Jian Bin Zhang, Yao Ning Sun, Ding Fan, Min Zheng
Abstract: Three compositions, (Ni75Si25)-5Cr, (Ni75Si25)-10Cr and (Ni75Si25)-15Cr, have been
cladded onto Ni-based suaperalloy substrate by pre-placing laser cladding process with a 5 kW
continuous wave CO2 laser. Ni75Si25 was also cladded with the same method for comparison. The
process parameters have been optimized to obtain defect free claddings. The microstructure and the
hardness of the cladded layers were characterized by optical microscopy, scanning electron microscopy,
X-ray diffraction and microhardness measurement. The corrosion resistance of the cladded layers was
measured in a sulfuric acid solution.
1319
Authors: Jian Bin Zhang, Ding Fan, Min Zheng, Yao Ning Sun, Yu Feng Zheng
Abstract: The applications of titanium and titanium alloys under severe wear conditions are highly
restricted due to their low hardness and poor tribological properties. To improve the hardness and wear
resistance, laser cladding of commercial purity titanium was carried out with a 5 kW continuous wave
CO2 laser. WC powders and Ti powders were mixed for cladding in different proportions. The phases of
clad layer were characterized by scanning electron microscopy, X-ray diffractometer and energydispersive
X-ray spectroscopy. The mechanism of the reaction between melted WC and Ti is discussed.
1316
Authors: Ding Fan, Yao Ning Sun, Min Zheng, Jian Bin Zhang, Yu Feng Zheng
Abstract: Laser cladding experiment was carried out with a 5 kW continuous wave CO2 laser by preplacing
Ni75Si25 and Ni78Si13Ti9 powders onto Ni-based superalloy substrate. The microstructure of
the specimens was monitored by using optical and scanning electron microscopy. The chemical
compositions of the alloys and their phases were obtained using X-ray diffraction and energy dispersive
x-ray spectroscopy. The phase transformation temperatures were determined by non-isothermal
differential scanning calorimetry tests. The microhardness of the laser cladded sample was measured.
1143
Authors: Jian Bin Zhang, Ding Fan, Yao Ning Sun, Yu Feng Zheng
Abstract: Surface modification is a promising technique to improve wear properties of titanium and
titanium alloys by modifying either the surface composition or microstructure. Laser remelting and
laser nitriding of commercial purity titanium were carried out under pure argon and pure nitrogen
ambient, respectively. Characterization of the laser treated surface was done by optical microscopy,
scanning electron microscopy (SEM), X-ray diffraction (XRD), microhardness tester. During laser
irradiation heating, Ti exhibits a height activity and combines with N in the atmosphere of pure
nitrogen forming TiN and TiN0.3, whereas Ti only transform into martensitic Ti in pure argon. The
Vickers microhardnesses are greatly improved by laser remelting and laser nitriding.
1745
Authors: Yao Ning Sun, Ding Fan, Ming Sun, Yu Feng Zheng, Jian Bin Zhang
Abstract: Laser cladding technique was used to form Ni3(Si,Ti) intermetallic coating by Nb addition
on Ni-based superalloy substrate. The coating was investigated by optical microscopy and X-ray
diffraction (XRD). The clad coating was dense, compact and smooth. An excellent bonding between
the coating and the substrate was ensured by a strong metallurgical interface. Ni3(Si,Ti) phase was
detected in all of the claddings, and NbNi3, Nb3Ni2Si were detected in Nb additional experiments. The
peaks intensity of Nb3Ni2Si and NbNi3 increased with the increasing of Nb content. The Ni3Nb and
Nb3Ni2Si were formed when Nb was beyond its solubility in the L12 Ni3(Si,Ti). The average
microhardness of the coating was improved with the increasing of the Nb content. The microhardness
was up to 530Hv when the atom percentage of Nb addition reached 5%, and it was much greater than
that of Ni-based superalloy substrate.
1716