Authors: Xiuling Zhang, Jan Kallweit, Mark Pätzel, Dana Kremenakova, Jakub Wiener, Kai Yang, Jiri Militky
Abstract: The textile industry has been weaving polymer optical fibers (POFs) into plane fabric for many years for lighting and decoration. To apply POF-incorporated fabrics in a larger field of application, it is necessary to improve the side illumination of POF-incorporated fabrics. It has been reported that the chemical etching method is one method to enhance the illumination of POFs, while there is little research related to the application of chemical etching to enhance the illumination of POF-incorporated fabrics. In this work, the end emitting POFs (EEPOFs) were used as weft yarns, and polyethylene terephthalate (PET) yarns were used as warp yarns. The POF-incorporated woven PET fabrics were successfully fabricated with a 1/3 twill structure and then treated with a mixture of acetone and methanol (volume ratio: 1:1) for 1 min. The morphology and side illumination of etched POF-incorporated PET fabrics were investigated. As a result, the acetone/methanol mixture destroyed the cladding layer of EEPOFs, and the luminance of etched POF-incorporated PET fabrics was increased by more than 50 %. Besides, acetone/methanol etching resulted in a higher side illumination attenuation behavior.
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Authors: Putera Anugrah Dhira Atmaja Perdana, Hary Sulistyo, Muhammad Mufti Azis
Abstract: Glycerol is an important chemical and widely used in many applications. Glycerol can be produced from a biodiesel industry as a by-product. In order to improve the economic value of glycerol as a by-product, it can be reacted with acetone to form solketal. Solketal can be used as a fuel additive to increase octane number. Reaction between glycerol and acetone can be catalyzed by Amberlyst-36. The objective of present study was to investigate the effect of mole ratio of glycerol:acetone and reaction temperature to the glycerol conversion. The process of acetalization was conducted in a batch reactor equipped with heater, temperature control, cooler and stirrer. The weight of catalyst was set on 5% based mass of glycerol and the stirrer speed was set on 650 rpm with reaction time of 3 hours. The mole ratio of glycerol to acetone was varied at 1:3, 1:4, 1:5 and 1:6, and the temperatures were varied on 40, 50 and 55 °C. The results showed that the highest conversion was 86.61 %, which was obtained at 120 minutes reaction, 50 °C and 1:6 mole ratio.
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Authors: Durgaprasad Gangodkar, Lalita Rane, Sai Ashish Kumar Karanam, Pratibha Daware, Gem Taka, Bhaskar Roy
Abstract: To meet future social and environmental objectives for diagnosis of human diseases has offered to develop the proficient gas sensors devices with higher selectivity and sensitivity. For the production of ZnO doped reduced graphene oxide (ZnO doped rGO) nanocomposite, a one-pot hydrothermal approach. The morphological, structural and composition of nanocomposite were investigated to confirm ZnO nanoparticle effectively doped on rGO nanosheets. The nanocomposite has exhibited a superior acetone sensing characteristics. Furthermore, the nanocomposite has a high selectivity for acetone vapour. These findings emphasise advantageous synergistic effects among ZnO and excellent rGO sheet substrate properties.
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Authors: I.V. Zaporotskova, D.E. Vilkeeva, L.S. Elbakyan
Abstract: This article provides a theoretical study of the possibility of reacting acetone, a common volatile organic compound (VOC) in human respiration, with carbon nanotubes modified with functional groups - carboxyl and amine. Analysis of efficiency of processes of sorption interaction of acetone molecule with modified nanosystem for development of recommendations for creation of perspective highly sensitive sensory devices using modified carbon nanotubes for detection of VOCs contained in human exhalation and diagnostics of various diseases.
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Authors: S.M. Basha, M.M. Basha, N. Venkaiah, Mamilla Ravi Sankar
Abstract: Fused Deposition Modelling (FDM) is one of the additive manufacturing processes which can produce prototypes or functional components without the use of fixtures, and the lead time required is reduced drastically compared to traditional machining processes. The application of the FDM process in the biomedical and casting industries is limited by its poor surface roughness which is most generally caused by the staircase effect and chordal error of the 3D model. Owing to the drawbacks of mechanical based finishing techniques, researchers have come up with a new technique known as Vapour Smoothing (VS). In this work, past literature of the VS process of FDM components is reported and it has been seen that the VS process is giving a promising improvement in surface roughness of FDM components.
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Authors: M.S. Lekshmi, K. Arun, K.J. Suja
Abstract: Metal oxide semiconductor has been widely used for breath analyzer applications. In this work, Acetone gas is the target gas as it an important breath marker for diabetes disease. Among the different p-type metal oxide nanostructures, Nickel oxide nanospheres are used as the sensing material as it is a promising candidate for Acetone sensing. The variation of resistance of the sensing material with the concentration of the target gas was analyzed. As Acetone is a reducing gas, the resistance of the sensing layer was found to increase when the sensing layer was exposed to the target gas. The simulation was done using COMSOL Multiphysics.
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Authors: Xiang Xiang Fan, Meng Ru Li, Lan Tian Xie, Ya Juan Xu, Wu Ming He, Xu Huang, Meng Jia Zeng, Pan Dai
Abstract: Acetone is a main respiratory marker for diabetic patients. In this paper, P-type NiO nanofibers were prepared by electrospinning and used for the detection of acetone gas. NiO nanofibers were characterized by SEM and XRD. The uniform NiO nanofibers with face-centered cubic structure was obtained. The working temperature of NiO nanofibers was optimized, and the optimal operating temperature is 220°C. The response-recovery curve was tested, and the response and recovery time is 24.6 s and 610 s respectively. The response to different concentrations of acetone was also analyzed, and the detection limit was 100 ppb. These results show that NiO nanofibers based on electrospinning have potential applications in the respiratory testing of diabetes.
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Authors: Harry Miyosi Silalahi, Wei Fan Chiang, Chia Yi Huang
Abstract: Poly hydroxyethyl methacrylate (p-HEMA) has a natural property that is very easy to absorb a liquid or solution and become a hydrogel when absorbing water. In this work, by combining p-HEMA material with a cholesteric liquid crystal (CLC), the material can absorb the solution and the optical properties of the liquid crystal will change depending on the solution it absorbs. The solution used in this work is acetone. During the absorption process the p-HEMA material expanded so that the orientation direction of liquid crystal molecular twist with a helical axis along can freely move and change. In this work, we observed the study of transmittance caused by thickness effect and the mixture concentration effect of the poly hydroxyethyl methacrylate liquid crystals (PHM-LC).
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Authors: Antonio Coppola, Filomena Impero, Cuono Ruggiero, Fabrizio Scala, Antonino Squillace
Abstract: Fused deposition modeling (FDM) is an additive manufacturing technology where three-dimensional physical models are manufactured by layer-by-layer deposition. However, the layered surface built with FDM suffers from poor surface quality and dimensional accuracy even for basic part geometries. This proves to be unacceptable and not satisfactory for most general purposes with the consequence of a decreased value of the final product. Several methods for post-processing were proposed to achieve fine surface of manufactured components. In particular, for components manufactured with polylactic acid (PLA) the chemical post-processing with dimethyl ketone (acetone), named vapor smoothing process, seems to be very promising to significantly improve the surface roughness. Moreover, acetone has the main advantage to have a low cost, low toxicity and high diffusion rate. However, this polishing procedure may dissolve the outer surface of the parts affecting the structural reliability of the part. In this work, a novel device, consisting of a cylindrical chamber in Pyrex, is set-up for the vapor smoothing process with acetone. The system is designed to permit the injection of a gas containing acetone at different concentrations and at different operating conditions (temperature, contact time). The samples used for the test are truncheon design manufactured using different printer settings; each truncheon is built at inclination angles varying from 0° to 45° in step of 5°. The variation of the surface roughness was investigated using a confocal microscope Leica DCM3D, equipped with the software LeicaScan and LeicaMap.
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Authors: Elin Karlina, Nina Djustiana, Renny Febrida, Yanwar Faza, Seniyah Seniyah, Camellia Panatarani, I Made Joni
Abstract: Nano size of ceramic filler (nanofiller) are tend to possess difficulties to be covered by resin matrix due to large surface area to volume ratio. Addition of aceton known as the diluent agent by introducing more content of filler as well as helping distribution of the filler in the resin matrix in application of dental composite restoration. In this study, a total 24 specimens of dental composite prototype; nanofiller-TMPS and nanofiller-MPTS were prepared using a customized acrylic mold and they were divided into two groups based on filler/resin ratio (n=6 each group). In the process of dental composite making, acetone were added into resin; 1 ml (filler/resin, 50/50) and 5 ml (filler/resin, 80/20) untill specific consistency obtained. The specimens were stored in distilled water for 24 hours at 37°C then subjected to hardness test using Vickers hardness tester machine, LECO – Japan M– 400–H1 with the load of 200 grams for 15 seconds (ADA Specification No. 27). Data were statistically analyzed using t independent test (α=0.05). The result revealed that dental composite prototype contain nanofiller-MPTS with filler/resin rasio (50/50) were statistically significant higher than dental composite prototype contain nanofiller-TMPS with same ratio (p<0.05). Otherwise, dental composite prototype with filler/resin ratio (80/20) were no observed statistically significant differences for both nanofiller-TMPS and nanofiller-MPTS (p>0.05). As conclusion, nanofiller modified MPTS are more effective to elevate surface hardness of dental composite prototype than nanofiller-TMPS for 50/50 filler/resin ratio
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