Papers by Keyword: Alcohol

Abstract: The increasing demand for sustainable energy solutions has intensified research into biodiesel production, which relies on chemical catalysts that have an environmental impact. This study investigates the alternative methods of biodiesel production by utilizing agricultural waste, specifically rice husk, coconut husk, and chicken manure as a catalyst for biodiesel production. Laboratory experiments were conducted to extract metal oxide from agricultural waste to be used as a catalyst in the transesterification process. The obtained ash was characterized, and it was revealed that rice husk ash contained 98% SiO₂, coconut husk ash had 72.62% of K₂O, and chicken manure ash had 46.56% CaO, with higher metal oxide compositions in each material. The transesterification reaction was conducted by varying alcohol to oil ratio from 3:1, 6:1, 9:1, and 12:1, temperature (40-80°C), catalyst concentration (1.5-4.5%wt), and reaction time (20-120min) to assess catalyst efficiency. Pure CaO was used as a control catalyst for comparison. Characterization of the produced biodiesel from all catalysts was conducted and compared to ASTM D6751 standards. The results for acid value, moisture content, density, viscosity, free fatty acid, flash point, pour point, and cloud point were analyzed and found to comply with ASTM D6751 standards. On quantity determination of produced biodiesel, the most effective catalyst was chicken manure ash with a yield of 80% and the least effective catalyst was rice husk ash with 68% yield. Using agricultural waste reduces up to 40% production cost.

Abstract: Although fossil fuel continues to play a dominant role in global energy system unfortunately their life span is threatened as the fossil reserves are running out. Except for the fact that they are readily available, tried and tested, unfortunately they bring about a negative environmental and climate impact. When the fossil fuels are burned, they produce both carbon dioxide and carbon monoxide which is the largest driver of global climate change and air pollution. This has caused a need to explore and transition to a cleaner and renewable energy resource like biofuel. Biofuel is a combination of fatty acid alkyl esters achieved by the esterification and transterification of triglycerides that can either be animal fats and vegetable oil with methanol and ethanol. Biodiesel provides several positive benefits by helping in decreasing the country’s dependence on the importation of crude oils, it also reduces the greenhouse gas emissions and advances the lubricating property. Biodiesel is produced and deployed globally with China being the country with the highest biofuel capacity in the world, with nearly 29.8 gigawatts as of 2021. It is followed by Brazil which is ranked second, with a biofuel capacity of 16.3 gigawatts. The selection of a feedstock in biofuel production has a noticeable impact as it determines if a biofuel will be formed or not from the transesterification process performed. The fatty acid / triglyceride content especially the Mono-Unsaturated Fatty Acids (MUFA’s) are of interest. The higher the MUFA’s, the higher possibility of a successful transterification hence biofuel being the by-products/formation with less catalyst and alcohol used. Feedstocks with over 40% fatty acids, especially the MUFA’s are favorable for biodiesel formation. Almost 80% of Macadamia’s fatty acids (MFAs) are palmitoleic acids (C16:1; ~20%) and Monounsaturated, mostly oleic (C18:1; ~60%). This study reviews the preparation of biofuel utilizing Macadamia nut oil (MNO) as a feedstock for sustainable biodiesel Production.

Abstract: Biogas quality in many installation of anaerobic digester for processing organic waste are found not optimum, especially in developing country where understanding of anaerobic processing is not well known. The methane content in the biogas are usually low that make it not possible to be utilized as a fuel of the engine. Biogas Purification usually will be introduced as a solution. But this idea is about complicated for simple or small anaerobic digester. Other solution is suggested by using enrichment of biogas by using other fuel such as hydrogen or blended with city gas such as LPG gas. But for preparing hydrogen gas or commercial will also costly. This research introduces simple technique for biogas enrichment by using denatured alcohol. The biogas contents were found around 30% vol. methane (CH₄) and around 2% Carbon dioxide (CO₂). The price of denatured alcohol is relative cheap because the selling tax is not as much as drinking alcohol. Engine with bigger combustion (420 cc) chamber was prepared for this purpose to make possible to be fueled with biogas. The compression was set to reach 10 bar. The clearance of the both intake and exhaust valve was set in order to be possible to be running by using biogas. The biogas-air mixer was design for this purpose. The carburetor was set for use of denatured alcohol. It is found that the engine is running well by using biogas fuel that is enriched by using denatured alcohol. The emission was found better comparing using gasoline for the same engine. The fuel consumption is reported for future economic analyses.

Abstract: Amine compounds are widely found in natural products, pharmaceuticals and fine chemical products. Therefore, it is of great significance to develop methods for synthesizing amine compounds. Therefore, in recent years, a new method of synthesizing amines has been developed, namely "hydrogen borrowing reaction". This article reviews the alkylation of primary alcohols and amines, the cyclization of amino alcohols to form N-heterocyclic compounds, the reaction of diols and amines to form N-heterocyclic compounds, the reaction of alcohols and sulfonamides, and the reaction of alcohols and amines containing N heteroatoms , Alcohol and ammonia gas and ammonia to produce amine by hydrogen reaction research progress.

Abstract: Mouthwash is an additional mechanical oral cavity cleaning method which is known to reduce oral bacterias that causes plaque build ups. Mouthwash may and may not contain alcohol. The objective of this study was to determine the alterations on the oral cavity environment (salivary pH and plaque index) before and after gargling with alcohol and non-alcohol mouthwash, and to analyze which of the mouthwash is more effective. This study was an experimental study with one group pre test and post test experimental design. The subject of this study was 16 of University of Sumatera Utara’s female undergraduates whose age ranges from 18–23 years old and accorded to the inclusion and exclusion criteria. Subjects were divided in two groups, subjects were instructed to used the mouthwash twice a day for seven days, then salivary pH and plaque index were measured at third and seventh day of used. Repeated Annova test results shown a significant decreas on salivary pH and plaque index after gargled with mouthwash containing alcohol, in the non-alcohol mouthwash there was a significant decreased in plaque index but none on the salivary pH. Dependent T-test results shown that there were no difference in salivary pH and plaque index after gargled with alcohol containing and non-alcohol mouthwash. This study shows that non-alcohol mouthwash is better because there were a significant decrease in plaque index, without caused significant decreases in pH scores.

Abstract: Silica nanoparticles are a very promising functional material when purified from silica sand for wide application. In addition, a low cost and easy method to obtain the material will be increasing the value of silica sand. To synthesize of nanoparticles using an easily scalable, cheap and simple method, we suggest a sodium silicate solution as a precursor that silica sand was diluted on the NaOH. After that, the sodium silicate solution under various alcohols (methanol and ethanol) in the acid medium was conducted by sol gel method to obtain silica nanoparticles. The synthesized of silica nanoparticles was observed to the non-agglomerate, homogeneous and spherical shape with an average size about 200 nm. We also noted the existence of NaNO₃ by side product of reaction on the system, which may be the amorphous silica unidentified on the XRD results.

Abstract: In vinegar production, there are several groups of microorganism consortium acting at different stages at each time. In the first step of alcoholic fermentation process, molds and yeasts are also crucial for vinegar fermentation, yielding sugar contents by accelerating the first step of vinegar fermentation of high ethanol production in the fermentation if the raw materials have complex components such as starch, cellulose, hemicellulose, pectin. Most dominant fungi species identified to be molds Aspergillus spp. had activities in breaking starch into sugar moiety in the present of oxygen. In the study, isolates of Aspergillus spp. were tested for their sugar production containing high contents from various cellulosic materials.

Abstract: Fresh fruit vinegar fermentation is well known for the activities of diverse groups of microorganisms at two stages of the fermentation process. Their species diversity depend on the raw materials fermented. In the study, at the first step of high sugar production, less culturable acetic acid bacterial species but more Aspergillus spp. and yeasts, non-Saccharomyces were detected. At the end, the vinegar production step, the fermented broth showed only dominant acetic acid bacteria. In the study, yeasts and fungi were isolated and inoculated to the juice. The results showed that these consortium could help increase high alcohol and later more acetic acid production when compared with the control fruit vinegar fermentation.

Abstract: This design of alcohol detection system uses DSP technology, ADF4350 frequency synthesizer chip developed microwave source controlled by DSP controller, the source excites the microwave resonator cavity, the output signal of the resonator is detected by the detector, then sampled and processed by the DSP processor, and the concentration of alcohol is calculated by perturbation theory and dielectric properties of alcohol. The human-computer interaction of this system is realized by touch screen, so that the display looks easy to operate and very user-friendly. This paper analyzes the feasibility of microwave resonant cavity perturbation method in alcohol materials, and derives the relationship between the concentration of alcohol mixed solution, the dielectric constant and the output frequency of the resonant cavity, and the theoretical basis of this paper is derived. The dielectric properties of different alcohol concentration at different frequencies were studied, and the standard curves of different concentration alcohol dielectric spectra were established by the theoretical model and a large number of experimental data.

Abstract: The effect of chemical solutions on the dispersion of single-walled carbon nantubes (SWCNTs) was studied. The SWCNTs were dispersed using several chemical solutions such as isopropyl alcohol (IPA), dichloromethane (DCM), acetone and triton X-100 (Triton-X) under ultrasonically process. The results show that the types of chemical solutions greatly affect the dispersion of SWCNTs. The IPA solution is found to be the best solution to disperse SWCNTs using ultrasonication process due to the difficultly of evaporation in room temperature to get a transparent solution.